Remember that a map is a section. It is an intersection of the ground with the subsurface geology. A syncline with an axis dipping at 20 deg projects an outline of itself onto the 3-D - ground surface and hence onto the 2D map surface. You just have to reverse those projections in your mind in order to envisage the 3-D structure.
Unconformities are easily recognisable, since one lithology will cut across several others. Unless we are dealing with thrust faults, or igneous intrusions then the truncated lithologies are the older ones.
It's really just a mater of putting together common sense ideas like that and practising the art of interpretation.
Apart from that, I'm with Matt - I don't understand what it is you don't understand.