How Does Adding KSCN Affect Fe3+, SCN-, and FeSCN2+ Concentrations?

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SUMMARY

The discussion centers on the effects of adding KSCN to a diluted FeSCN solution in a lab experiment testing Le Chatelier's Principle. When KSCN is introduced, the concentration of SCN- increases, leading to a color change from orange to yellow. The participants conclude that the iron concentration does not remain constant due to the dilution effect, and the reaction likely shifts to the left, favoring the reactants rather than indicating a true equilibrium shift.

PREREQUISITES
  • Understanding of Le Chatelier's Principle
  • Knowledge of chemical equilibrium concepts
  • Familiarity with colorimetric analysis in chemistry
  • Basic skills in preparing stock solutions and dilutions
NEXT STEPS
  • Research the principles of chemical equilibrium and shifts in reaction dynamics
  • Study the effects of dilution on reaction concentrations
  • Explore colorimetric methods for measuring concentration changes in solutions
  • Investigate the role of ligands in complex ion formation, particularly with Fe3+ and SCN-
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Chemistry students, educators conducting laboratory experiments, and anyone interested in understanding chemical equilibrium and reaction dynamics.

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Homework Statement


During class we did a lab testing Le Chatelier's Principle where we took FeSCN-(aq) and added water in order to dilute it to a lighter colour (red to orange) and to make a stock solution. We then divided the stock solution into several test tubes. In one of them we added KSCN.

The question asked is:

How does the concentration of Fe3+(aq), SCN-(aq) and FeSCN2+(aq) change if the KSCN is added to the test? What remains constant? What kind of shift is involved?

Homework Equations

The Attempt at a Solution



I just need clarification to see if I'm doing this correctly. When we add KSCN to a test tube with the stock solution the solution went from orange to yellow. When it asks about how the concentration changes, it changes because there is more KSCN added. Meaning there will be more SCN-(aq), would this be correct? Pertaining to the question what remains constant would that just simply be the iron? And lastly what kind of shift involved would be a shift to the left because it favors the reactants.
 
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Veronica_Oles said:
Pertaining to the question what remains constant would that just simply be the iron?

You have changed the total volume, how can the iron concentration remain constant?

I can be wrong, but at a first sight looks like the experiment is a bit misleading. Color change is most likely effect of dilution, not of a shift in the reaction.
 
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Borek said:
You have changed the total volume, how can the iron concentration remain constant?

I can be wrong, but at a first sight looks like the experiment is a bit misleading. Color change is most likely effect of dilution, not of a shift in the reaction.
Oh okay that makes sense
 

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