How does atomic absorption spectroscopy work

Click For Summary
SUMMARY

The discussion centers on the principles of atomic absorption spectroscopy (AAS) as applied in a laboratory experiment to calculate the Rydberg constant for hydrogen. The experiment utilized a hydrogen lamp and a spectrometer connected to a photomultiplier tube (PMT) to detect specific wavelengths of light from the Balmer series. Participants clarified that the technique measures the reemission of light from atoms when the incoming light is resonant, confirming that the method remains classified as absorption spectroscopy due to the monochromatic nature of the light source.

PREREQUISITES
  • Understanding of atomic absorption spectroscopy (AAS)
  • Familiarity with the Balmer series of hydrogen
  • Knowledge of spectrometer operation and function
  • Basic principles of photomultiplier tubes (PMTs)
NEXT STEPS
  • Research the principles of atomic absorption spectroscopy (AAS) in detail
  • Learn about the Balmer series and its significance in spectroscopy
  • Explore the operational mechanics of spectrometers and their components
  • Study the role of photomultiplier tubes (PMTs) in detecting light intensity
USEFUL FOR

Students and educators in chemistry, laboratory technicians, and researchers interested in spectroscopy and atomic interactions.

Login
Messages
12
Reaction score
0
TL;DR
If electrons absorb light, how can the spectrometer detect those wavelengths?
I did a prac where we tried to calculate the rydberg constant for hydrogen. We had a hydrogen lamp and we used a spectrometer that was hooked up to a photomultiplier tube to detect the wavelengths of light corresponding to the balmer series. In one section I need to write up a brief summary of how the experiment works, but I don't fully understand it. The explanation in our lab doc says light from the source is diffracted by the spectrometer and focused onto an exit slit so that only a particular wavelength of light can be transmitted to the detector at anyone time. Are we measuring the emissions of the electrons? If not, then what are we measuring? It can't be the lack of spectral lines since our PMT showed spikes in intensity at wavelengths that correspond to the balmer series. If we are measuring the emissions why isn't this just atomic emission spectroscopy?
 
Physics news on Phys.org
Is there some kind of schematic in the lab instructions?

It could be that you are measuring the reemission from the atoms, which will happen when the incoming light is resonant. It would still be absorption spectroscopy as the light source is monochromatic. From emission spectroscopy you would excite the atom thermally and analyse all emitted light to see which wavelengths are being emitted.
 

Similar threads

  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 6 ·
Replies
6
Views
1K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 4 ·
Replies
4
Views
3K
  • · Replies 9 ·
Replies
9
Views
3K
  • · Replies 1 ·
Replies
1
Views
1K
  • · Replies 4 ·
Replies
4
Views
3K
Replies
8
Views
5K
  • · Replies 2 ·
Replies
2
Views
3K
  • · Replies 3 ·
Replies
3
Views
2K