How Does Doubling Zinc Mass Affect Temperature Change in ZnO Formation?

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Discussion Overview

The discussion revolves around the effects of doubling the mass of zinc on the temperature change during the formation of zinc oxide (ZnO) through a reaction with hydrochloric acid (HCl). It explores theoretical implications and calculations related to heat evolved and enthalpy changes in a chemical reaction context.

Discussion Character

  • Technical explanation
  • Mathematical reasoning
  • Debate/contested

Main Points Raised

  • One participant suggests that increasing the mass of zinc leads to more zinc particles, resulting in increased collisions and higher average kinetic energy, thus raising the temperature change.
  • Another participant points out that the question may be poorly worded, indicating that the answer depends on identifying the limiting reagent in the reaction setup.
  • It is noted that the amount of heat produced is directly proportional to the amount of zinc that reacts, assuming sufficient excess of acid is present.
  • A later reply confirms that zinc was identified as the limiting reagent in the context of the discussion.
  • One participant states that the heat evolved (q) is an extensive property, implying it scales with the amount of substance involved.

Areas of Agreement / Disagreement

Participants express differing views on the clarity of the question and the factors influencing the temperature change, indicating that multiple competing views remain regarding the relationship between zinc mass and temperature change.

Contextual Notes

The discussion highlights dependencies on the limiting reagent and the presence of excess reactants, which may affect the conclusions drawn about temperature change and heat evolved.

Who May Find This Useful

This discussion may be useful for students and practitioners interested in thermochemistry, reaction kinetics, and the principles of limiting reagents in chemical reactions.

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Homework Statement
I'm having trouble understanding whether q stays constant? If it does, then for part b) does q stay the same?
Relevant Equations
q = mcdeltaT
Experiment equation: Zn(s) + 2HCL(aq) -> 2ZnCl(aq) + H2(g)

a) If the the mass of zinc solid used was doubled, what effect would this have on temperature change?

Answer: if mass of zinc increases, there will be an increase in zinc particles which increases the collisions between particles and increases the average kinetic energy therefore giving higher temperature change

b) What would have been the number of joules evolved (q)?

c)What effect would this have on delta H?
delta H would increase by a factor of 2 since the mass is doubled, so the number of mols has also doubled.
 
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Question is a bit poorly worded or you posted it incomplete, as the answer depends on several other factors - mainly on what is the limiting reagent in the setup.

Amount of heat produced is directly proportional to the amount of zinc that reacted.

Q is not much different from ΔH in that regard (see your answer to c.) - assuming there was a sufficient excess of acid.
 
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Thx for your reply. I have figured out the answer as I realized that zinc was the limiting reagant.
 
Yes, q is an extensive property.
 

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