How does the Winkler Titration Method work and what is the chemistry behind it?

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SUMMARY

The Winkler Titration Method is utilized for measuring dissolved oxygen in water samples. In this discussion, magnesium sulfate and sodium iodide were used instead of the traditional manganese sulfate and potassium iodide. The participants questioned whether magnesium sulfate can effectively replace manganese sulfate and if sodium iodide serves the same purpose as potassium iodide in the titration process. The chemistry behind the method involves redox reactions that are critical for accurate dissolved oxygen measurements.

PREREQUISITES
  • Understanding of redox reactions in chemistry
  • Familiarity with titration techniques
  • Knowledge of dissolved oxygen measurement methods
  • Basic chemistry of manganese and iodine compounds
NEXT STEPS
  • Research the chemical reactions involved in the Winkler Titration Method
  • Learn about the roles of manganese sulfate and potassium iodide in titrations
  • Investigate alternative methods for measuring dissolved oxygen
  • Explore the implications of using magnesium sulfate in place of manganese sulfate
USEFUL FOR

Chemistry students, environmental scientists, and laboratory technicians involved in water quality testing and analysis.

dazza95
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We used the winkler titration method for our dissolved oxygen experiments.
We added magnesium sulphate and sodium iodine.
For all the methods on the internet it says to use manganese sulphate and potassium iodide.
We have to explain how the method works and the chemistry behind it, so does the magnesium sulphate do the same job as the manganese sulphate likewise the sodium iodine does the same job as potassium idodie?
 
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dazza95 said:
We have to explain how the method works and the chemistry behind it

http://lmgtfy.com/?q=winkler+titration

Now, once you will read about the method, at least magnesium/manganese part should be obvious.

I am moving the question to the homework section - as this IS part of your homework.
 

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