The naive expectation is true for all numbers except 3, 6, and 9 (the naive expectation being number of permutations of 1-k divisible by k is (k-1)!). For example:
For 2: 12, 21, where one ((2-1)! = 1! = 1) of them is divisible by two.
For 3: 123, 231, 312, 132, 321, 213 - all of them divisible by three.
You now have a + b + 2c + 3d + 4e + 5f + 6g mod 7, where a-g are is a permutation of 1-7. The trick here is to show that for a given permutation which is divisible by 7, there are also 6 which are not - any element of the permutation group with order 7 should do (although some may be more suited than others).