How to make 0.2 M Tris-Acetate Buffer pH 6

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Discussion Overview

The discussion centers around the preparation of a 0.2 M Tris-Acetate Buffer at pH 6, exploring the feasibility and methodology for achieving this specific buffer composition. Participants examine the theoretical and practical implications of using Tris at this pH level, as well as alternative approaches based on literature references.

Discussion Character

  • Technical explanation
  • Debate/contested
  • Experimental/applied

Main Points Raised

  • One participant inquires about the protocol for making a 0.2 M Tris-Acetate Buffer at pH 6, referencing a method for pH 8.
  • Another participant argues that preparing a Tris-Acetate buffer at pH 6 is outside the buffering range of both acetate and Tris buffers, suggesting that it may not function effectively as a buffer.
  • A participant cites a literature reference that describes the use of a 0.2 M Tris-Acetate buffer at pH 6 in a specific experimental context, seeking advice on how to proceed with this method.
  • One suggestion is made to adjust the final pH using a pH meter to achieve the desired pH level.
  • Another participant notes that using Tris at pH 6 would be ineffective due to its pKa, and suggests that hydroxylamine, which has a pKa close to 6, may be providing the buffering capacity instead.

Areas of Agreement / Disagreement

Participants express disagreement regarding the viability of using Tris-Acetate at pH 6, with some asserting that it is outside the effective buffering range, while others reference literature that supports its use. The discussion remains unresolved regarding the best approach to prepare the buffer.

Contextual Notes

There are limitations regarding the assumptions about buffering capacity at low pH levels, and the dependence on specific experimental conditions as noted in the literature reference. The discussion does not resolve the mathematical or theoretical implications of using Tris at this pH.

Who May Find This Useful

This discussion may be of interest to researchers and practitioners in biochemistry or molecular biology who are looking to prepare buffers for experimental protocols, particularly those involving pH-sensitive reactions.

asy
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Hello,

I need to make a 0.2 M Tris-Acetate Buffer pH 6 and I can't find a protocol for this specific buffer.

I know that I can make a Tris solution (i.e. 12.11 g of tris(hydroxymethyl)aminomethane in water), adjust the pH to 8 and dilute to 1000 mL with water.

Is the same true for pH 6?

Thanks for the help
Regards
 
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TRIS acetate at pH 6 doesn't make sense, you are outside of the buffering range of both acetate buffer and TRIS based buffer. Quite likely that's why you can't find the recipe. Technically it is possible to prepare a solution containing both acetate and TRIS and having pH of 6, it just won't be a buffer.
 
Thanks for the feedback.
I'm trying to use a method that I found in the literature, which was cited in several papers.

Folk JE and Cole PW (1966) The Journal of Biological Chemistry 241(23): 5518–5525

"Each test was made in a final volume of 0.5 ml of 0.2 M Tris-acetate buffer, pH 6.0, containing 0.1 M hydroxylamine, 5 mM CaCl2, 10 mM GSH, and 30 mM CBZ-n-glutaminylglycine. After a 5 or 10 min incubation with the enzyme at 37 ºC, 0.5 ml of ferric chloride-trichloracetic acid reagent was added, and the resulting red color was measured at 525 nm."

Any suggestion how to proceed?
Thanks
 
You can't go wrong with adjusting the final pH with the pH meter.
 
Thank you for the help!
 
Yes the tris would be a poor buffer more than 2 units below its pKa.

But oh dear, the hydroxylamine has a pKa close to 6, and that is what must be doing most of the buffering during whatever reaction you are following. Just try doing whatever you are doing making your solution pH 6 without any tris! And tell us.
 

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