Hydrogen in Magnetic Field, Interaction Representation

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SUMMARY

The discussion focuses on the interaction of hydrogen in an external magnetic field represented by the vector $$ \textbf{B}=\hat{i}B_1 cos(\omega t) + \hat{j} B_2 sin(\omega t) + \hat{k} B_z $$ and its implications on the Hamiltonian. The Hamiltonian is expressed as $$ H = H_0 + H' $$, where $$ H' $$ incorporates time-dependent terms. The participants analyze the resulting differential equations for the spin states, specifically questioning the treatment of the term $$ B_z \sigma_3 $$ and its significance in the perturbation theory. The conversation emphasizes the necessity of including time-independent components in the Hamiltonian for accurate modeling.

PREREQUISITES
  • Quantum Mechanics, specifically the principles of spin and Hamiltonians
  • Understanding of time-dependent perturbation theory
  • Familiarity with the Schwinger-Tomonaga equation
  • Basic knowledge of differential equations and their applications in quantum systems
NEXT STEPS
  • Study time-dependent perturbation theory in quantum mechanics
  • Explore the implications of the Schwinger-Tomonaga equation in quantum dynamics
  • Learn about coupled differential equations in quantum systems
  • Investigate the role of time-independent Hamiltonians in perturbation theory
USEFUL FOR

Quantum physicists, students of quantum mechanics, and researchers working on magnetic field interactions with atomic systems will benefit from this discussion.

Muh. Fauzi M.
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The hydrogen is placed in the external magnetic field:
$$ \textbf{B}=\hat{i}B_1 cos(\omega t) + \hat{j} B_2 sin(\omega t) + \hat{k} B_z ,$$

Using the relation ## H = - \frac{e\hbar}{2mc} \mathbf \sigma \cdot \mathbf B ##, then I got the form

$$ H = H_0 + H' , $$

where

$$ H'= - \frac{e \hbar}{2 m c} (B_1 cos(\omega t) \sigma_1 + B_2 sin(\omega t) \sigma_2 ) .$$

To find the spin state in the interaction representation, I substitute the ## H' ## in

$$ i\hbar\frac{\partial}{\partial t} | \psi \rangle = H' | \psi \rangle , $$

with ## | \psi \rangle = \begin{pmatrix} a \\ b \end{pmatrix} .##

Next, I tried to solving it, e.g. for ## a ##

$$\frac{\partial^2 a}{{\partial t}^2} + \lambda^2 a = 0 ,$$

with

$$ \lambda^2 = \big(\frac{e}{2mc}\big)^2[B_1^2 cos^2(\omega t)+B_2^2(sin^2(\omega t))] .$$

Then I'm heading for the boundary condition.

But then I realized that the ## \lambda^2 ## is depend on ## t ##.

So, my question, is it "ok" to continue to the boundary condition, or there is something wrong with my attempt?
 
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How did you get the differential equation for a? It seems to me you should get two coupled differential equations involving a and b. Is what you show the decoupled result? Also, should you not include the term ##B_z \sigma_3## in your expression for ##H'##?
 
kuruman said:
How did you get the differential equation for a? It seems to me you should get two coupled differential equations involving a and b. Is what you show the decoupled result? Also, should you not include the term ##B_z \sigma_3## in your expression for ##H'##?
I don't include the ## B_z \sigma_3 ## because it time independent.

I realized that I don't differentiate with time the ##{B_1 cos (\omega t) \mp i B_2 sin (\omega t)}## term in the ##\partial a/\partial t## and ##\partial b/\partial t##.

Here's my result after differentiating it (for ## \partial a/\partial t ##),

$$ \frac{\partial^2 a}{{\partial t}^2} = - \frac{e\hbar}{2mc}\Big[ \frac{ie}{2mc} [B_1^2 cos^2{\omega t}+B_2^2 sin^2{\omega t}] a + \frac{2mc}{e\hbar} \omega i \frac{B_1 cos \omega t + i B_2 sin \omega t}{B_1 cos \omega t - i B_2 sin \omega t} \frac{\partial a}{\partial t} \Big] .$$
 
Muh. Fauzi M. said:
I don't include the Bzσ3 B_z \sigma_3 because it time independent.
So what? Is it not a perturbation to ##H_0##? As long as ##B_z \neq 0##, you cannot ignore it.
 
kuruman said:
So what? Is it not a perturbation to ##H_0##? As long as ##B_z \neq 0##, you cannot ignore it.

Thanks for your clue.

I am using Schwinger-Tomonaga equation, where the Hamiltonian that evolve with time is only the time dependent. CMIIW
 
update, I have finish this work.
 

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