Identity Matrix: Does AB=BA for Other Matrices?

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SUMMARY

The identity matrix is the only matrix that commutes with all other matrices, meaning for any matrix A, the equation IA = AI holds true. While there are specific pairs of matrices, such as the matrix \left[ \begin{array}{cc}0 & 1 \\ 1 & 0 \end{array} \right] and \left[ \begin{array}{cc}a & b \\ b & a \end{array} \right], that can commute with each other, they do not commute with arbitrary matrices. The identity matrix's commutative property is valid only when both IA and AI are defined.

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Is the identity matrix (or multiple of) the only one that commutes with other matrices or are there other matrices that AB=BA?

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Yes, those are the only ones that commute with all other matrices. There are pairs of matrices which aren't multiples of the identity matrix that commute with each other, like any matrix with a multiple or power of itself, or:

\left[ \begin{array}{cc}0 & 1 \\ 1 & 0 \end{array} \right], \left[ \begin{array}{cc}a & b \\ b & a \end{array} \right]

but they won't commute with an arbitrary matrix.
 
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The identity matrix commutes only when both IA and AI are defined.
 

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