If something becomes an ion, is its zeff changed?

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SUMMARY

The effective nuclear charge (Zeff) of an atom is influenced by the loss or gain of electrons. When an atom loses an electron, the shielding effect diminishes, resulting in an increase in Zeff. For example, in neutral helium (He), the Zeff is between 1 and 2, while in the helium ion (He+), the Zeff is exactly 2. This demonstrates that ionization alters the effective nuclear charge experienced by the remaining electrons.

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Bipolarity
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If some atom loses or gains an electron, is its effective nuclear charge changed? I would think that it would change, considering that having lost an electron the shielding effect weakens, making the zeff larger, but people are saying there is no effect? Is there some explanation?

THanks!

BiP
 
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Try to calculate Zeff using Slater's rules.
 
A simple counter example may also help. Consider He. In neutral He, the effective charge is somewhere between 1 and 2, while in He^+ it is exactly 2.
 

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