Unwinding the field configuration is forbidden classically due to topology. The simplest example is a one-dim. Sine-Gordon model where you compactify the one-dim. space dimension from R to S1. The winding number 1 cannot be contiuously deformed to 0 due to a conserved charge.
In quantum mechanics or quantum field theory one has to care about quantum fluctuations as well.This is where the energy barrier comes in. Due to the infirnite barrier even quantum fluctuations cannot destroy the soliton. This can be seen by calculating it explicitly for the Sine-Gordon model. Note that the "path" from winding numer 1 to zero is parameterized by a t-dependend function which is not a solution of the field equation. But this is not necessary as the quantum fluctuations need not be classical solutions.
The idea of the Skyrme model is based on chiral-effective theories taking into account low-energy degress of freedoms like pions only; or - in more general approaches - vector mesons in addition to pseudo-scalar mesons. One can even think about replacing SU(2)Flavor by SU(3)Flavor. These models a rather successful in describing pion-pion and pion-photon coupling, scattering cross section, form factors and things like that. But they do not contain spin 1/2 baryons and one is therefore interested in enlarging the models such that they can describe pion-nucleon coupling as well. Instead of introducing explicit nucleon spinor fields one tries to stay with the pions and allow them to form stable nucleon states. Now the problem is that one would need a kind of potential term for the pion fields, but one knows that pion-pion coupling is weak - which rules out a normal potential term. So instead of using a potential which binds pions to nucleons one tries to stabalize the nucleons with a topological effect.
It was clear from the very beginning that the so-called non-linear sigma-models with SU(2) pion fields contain a topological sector due to the winding number, but unfortunately such a soliton would collaps to zero size when one starts to minimize its energy. In the Skyrme model (or in vector-meson models) the nucleon is stabilized due to additional self-interactions of the meson fields (this self interaction does not change the soft two-pion interaction at low energies). The Skyrme model is an effective model where other vector-meson contributions have been integarted out.