Interatomic potential and binding energy system of equations

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Homework Help Overview

The discussion revolves around the interatomic potential and binding energy, specifically focusing on equations related to equilibrium bond length and constants A and B in the context of atomic interactions. Participants are examining the implications of their calculations and the significance of small numerical values in their results.

Discussion Character

  • Exploratory, Assumption checking, Mathematical reasoning

Approaches and Questions Raised

  • Participants are sharing their calculations and questioning the validity of their results, particularly regarding the small values obtained for constants A and B. There is an exploration of how to handle powers of ten in calculations and the implications of using different units.

Discussion Status

Several participants have provided guidance on recalculating values and the importance of unit consistency. There is an ongoing exploration of the implications of the small constants and their relevance to the physical context of the problem. Some participants are reflecting on their understanding of the constants and their significance in the equations.

Contextual Notes

Participants are encouraged to adhere to guidelines regarding the presentation of their work. There is a noted challenge in interpreting very small numerical values and their powers, as well as a discussion on the appropriateness of units used in the calculations.

KiNGGeexD
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I have attached a photograph of my problem to save time on typing the question
ImageUploadedByPhysics Forums1395851922.029679.jpg


I have done the first part to obtain the expression for equilibrium bond length and in the second part I solved that equation for A and substituted it into my binding energy equation and obtained an answer with the order of magnitude to the -60 so when I square it in my calculator I get 0, I'm assuming this is incorrect somehow although I don't see what I have done wrong
Thanks for any help in advanced, all necessary equations are present in the problem
 
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Broke my screen trying to read your picture without breaking my neck.
Please use the template. Read the guidelines to find out why saving your time typing is no good. Let alone breaking helpers' screens and/or necks!

Show your calculations. Upright. Then we'll check :smile:
 
Sorry I will post another photograph and will take a photo also of my calculations just now
 
ImageUploadedByPhysics Forums1395855710.394004.jpg
 
ImageUploadedByPhysics Forums1395855873.259840.jpg
This is what I have got! But I keep getting A as 0
 
Regardless of how I do it my numbers are far to small
 
If your calculator can't handle these small numbers, you can always leave out the powers of ten, calculate, and then add the powers of ten again -- by hand ! Not so difficult, actually.

Work a little more neatly. ##B^2/{4A}## is not 0.0031, so B is even smaller than you thought. Let alone A !

Still, the answer is correct. Remember that 1/r0^12 is huge !
 
Ok I will give it a bash
 
Ok so I recalculated for A using B as just 2.63 and leaving out the negative power, I obtained A to be 557.81

Now my only issue is powers, when I use these constants in the first equation though just as they are they work, because the ratios are the same but they don't in the second equation
 
  • #10
Sorry excuse my idiocy it does also work in the second equation :(

So my only issues is powers, one is to the negative 60 so if the ratio with the two numbers work then surely I have 557.81 to the negative 60 also,

Or
5.5781 to the negative 62?
 
  • #11
To the negative 58 rather, as it is larger haha
 
  • #12
Ok I redone all of my maths and wrote it out properly and got A= 5.576 to the negative 118When I put that back into my expression and used the laws of indices to make it simpler I got the correct answer which makes sense considering my powers which where then squared etcI do have a question regarding these constants? They are tiny... I mean an atom is what tens of femto metres so something to the negative 118 is over 100 orders of magnitude smaller
 
  • #13
Six posts! Which one do you want me to read ?

In the mean time, maybe you can read post 7
It has some clue as to why A needs to be pretty small.
 
  • #14
I know sorry I post and change my mind gaha but the post with A to the negative 118 is the right answers I'm sure I tried it in the equation
 
  • #15
It's much easier to use nm as your unit for distances instead of meters that way you avoid having to deal with the powers of 10 all together.
 
  • #16
KiNGGeexD said:
Ok I redone all of my maths and wrote it out properly and got A= 5.576 to the negative 118


When I put that back into my expression and used the laws of indices to make it simpler I got the correct answer which makes sense considering my powers which where then squared etc


I do have a question regarding these constants? They are tiny... I mean an atom is what tens of femto metres so something to the negative 118 is over 100 orders of magnitude smaller

Look at the units. A and B are not sizes. Their units are eV nm6 and eV nm12. You really should use nm instead of meters for that problem.
 
  • #17
I know they aren't sizes just extremely small I was just trying to get a sense of proportion as if they were sizes :)
 
  • #18
KiNGGeexD said:
I know they aren't sizes just extremely small I was just trying to get a sense of proportion as if they were sizes :)

But that doesn't work. The numbers in themselves are completely meaningless without the units and with the units it can only be compared to other quantities that have the same units. Mentioning the size of an atom without the units will not help you understand anything.
 
  • #19
Ok sorry haha! Are the constants ok though in terms of validity of the problem?:)
 
  • #20
KiNGGeexD said:
I know they aren't sizes just extremely small I was just trying to get a sense of proportion as if they were sizes :)
Good thing to try and assimilate some of the stuff just worked out. Physicist in the making! Start by googling Lennard-Jones potential.

Just so you know we're all human: I looked there first too, so I could assist without making too much of a fool of myself again :smile:
 

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