IR Spectrum Info: Benzaldehyde, Cinnamaldehyde, etc.

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    Ir Spectrum
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Discussion Overview

The discussion revolves around obtaining information related to the IR spectra of various organic compounds, specifically benzaldehyde, cinnamaldehyde, benzophenone, cyclohexanone, and acetophenone. Participants seek guidance on identifying the peaks associated with specific bonds within these spectra.

Discussion Character

  • Exploratory
  • Technical explanation
  • Homework-related

Main Points Raised

  • One participant expresses difficulty in finding information on the IR spectra peaks for the specified compounds and requests assistance in identifying which peaks correspond to which bonds.
  • Another participant suggests using databases such as the Sadtler database, NIST, Merck, and Aldrich for IR spectra, noting that different solvents may cause shifts in wavelength peaks.
  • A different participant mentions that IR spectra are typically observed with neat materials for liquids or oils and recommends checking the SDBS for a wide range of IR and NMR spectra for common compounds.
  • A participant shares a reference to "The Aldrich library of FT-IR spectra" as a potential resource.

Areas of Agreement / Disagreement

Participants generally agree on the usefulness of specific databases for obtaining IR spectra, but there is no consensus on the exact peaks corresponding to bonds for the compounds in question, as this remains unresolved.

Contextual Notes

Participants note that the context in which the spectra are obtained, such as solvent choice, may affect the observed peaks, indicating potential limitations in the data available.

OH group student
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i'm having fierce trouble trying to obtain information as to the peaks/bonds in the IR spectra of the following; benzaldehyde, cinnamaldehyde, benzophenone, cyclohexanone and acetophenone.

i keep typing in plenty of the keywords in the various search engines but to no avail.

all i need is a rough guide as to which peaks belong to which bonds!

can anyone provide a decent link to help me out?
thanks
 
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Try the sadtler database or the NIST, I think Merck and Aldrich has some good databases for these types of spectra. The thing is, they may have obtained the spectra in a different context, such as different solvents, for which there may be shifts in the wavelength peaks.

If this was for an experiment, you should have obtained each respective compound spectra independently.
 
IR spectra are usually observed with neat material if they are liquids or oils, which all of those are. You should certainly check to see that the specta are neat, however.

You should check out the SDBS, they have tons of IR and NMR spectra for common compounds.

http://www.aist.go.jp/RIODB/SDBS/cgi-bin/cre_index.cgi
 
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thanks a lot, will check em out.
:smile:
 
Book

The Aldrich library of FT-IR spectra
 

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