Is CuI2 Soluble in Water?

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Discussion Overview

The discussion centers around the solubility of CuI2 in water, with participants exploring related compounds and solubility rules. The scope includes theoretical considerations and chemical reactions involving copper and iodides.

Discussion Character

  • Debate/contested
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • Some participants suggest that CuI2 is insoluble in water, questioning how this fits with the general rule that iodides are soluble except for heavy metals.
  • One participant proposes that copper might be considered a heavy metal.
  • Another participant notes the lack of evidence for the existence of CuI2, complicating the discussion of its solubility.
  • There is a mention of a reaction involving KI and CuSO4, with confusion about whether it results in a double replacement or no reaction.
  • One participant claims that the reaction leads to a synthesis reaction and references a source indicating that CuI2 is insoluble, while expressing confusion about the solubility rules.
  • Another participant challenges the reliability of the source that lists CuI2 as slightly soluble, suggesting it may not be accurate.
  • There is a discussion about the oxidation of iodides by copper(II) in solution, leading to the formation of copper(I) iodide instead of CuI2.

Areas of Agreement / Disagreement

Participants express differing views on the solubility of CuI2, with no consensus reached. Some assert it is insoluble, while others question its existence and the reliability of sources regarding its solubility.

Contextual Notes

There are unresolved questions regarding the definitions of solubility and the specific behavior of copper in reactions with iodides. The discussion also highlights potential confusion between copper(I) and copper(II) iodides.

chemist2b
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are these soluble in water?

Na2Cr2O7 (i think yes)

(NH4)2Cr2O7 (i think yes)

PbCr2O7 (i think no)

CuI2 (no? whay is this disproving by rule that iodides and chlorides are soluble in water except for heavy metals?)
 
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Maybe copper is a heavy metal?
 
chemist2b said:
CuI2 (no? whay is this disproving by rule that iodides and chlorides are soluble in water except for heavy metals?)

There is no such compound, so it is hard to say if it is soluble.

This is a very specific case.
 
so this was the equation i was given: KI + CuSO4---> something

i assumed it was k2S04 and CuI2

this is supposed to be either no reaction or double repleacement

maybe having the whole equatoin helps?

but the other three were correct, right?
 
chemist2b said:
this is supposed to be either no reaction or double repleacement

Actually it is neither. And it is really not that difficult to check, some googling should help you quite fast.

but the other three were correct, right?

Yes.
 
so if i cancel out spectators, it is a synthesis reaction (most sites agree that cuI2 is insoluble in water)

Cu +2 (aq) + 2I -1(aq) ---> CuI2 (s)

what i don't understand is why it is disproving my solubility rule (iodides are insoluble except for heavy metals, and copper isn't a heavy metal).

ps. you can be awful at googling. if i was good at it i would probably not have to ask these questions here.
:(
 
Show me one site that lists CuI2 as insoluble.
 
hte site of the sheet that my teacher gave me. it says "ss" for slightly soluble which he told us to assume meant insoluble. but i gues the chart isn't that reliable. because llokibng now at the other ones i see mostly blanks but one or two say soluble. thanks...
 
chemist2b said:
hte site of the sheet that my teacher gave me. it says "ss" for slightly soluble which he told us to assume meant insoluble. but i gues the chart isn't that reliable. because llokibng now at the other ones i see mostly blanks but one or two say soluble. thanks...

Are you sure it shows solubility of copper(II) iodide and not solubility of copper(I) iodide?

In water solutions in the presence of iodides copper(II) oxidizes iodides to iodine and gets reduced to copper(I), this is followed by copper(I) iodide precipitation. CuI is weakly soluble, CuI2 doesn't exist.
 

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