Is Log of Molecules a Thermodynamic State Variable?

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The discussion revolves around whether the logarithm of the number of molecules can be considered a thermodynamic state variable. Participants are exploring the definitions and implications of state variables within the context of thermodynamics.

Discussion Character

  • Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants are questioning the nature of state variables and whether mathematical functions of state variables, such as the logarithm of the number of molecules, can also be classified as state variables. There are inquiries regarding the context of the original question and the definitions of state variables.

Discussion Status

The discussion is ongoing, with participants raising questions about the definitions and characteristics of state variables. Some guidance has been offered regarding the nature of physical quantities versus mathematical functions, but no consensus has been reached.

Contextual Notes

Participants are also discussing related concepts, such as the control of certain parameters and the classification of melting and boiling points as state variables, which may introduce additional complexity to the discussion.

keith river
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Is log (no of molecules) a state variable? I know that the no of molecules are a state variable so I assume the logarithm of this is still a state variable. Am I right?
 
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In what context did you bump into this question ? Why is ln N there ?
 
It was just a question I found in a thermodynamics question book. The full question is
"State whether these are state variables or not... (list of quantities)... logarithm of number of molecules"
 
What is a state variable ? You need to be sure about the notions before attempting an answer.
 
State Variables are parameters which describe a thermodynamic system.
Some are inherent in the system (eg specific heat capacity) and some we can control (eg heat capacity)

I suppose since we can control N then ln N is to an extent controlled, but I don't know if it counts as a state variable.

Also (quick question to check an answer I made) is the melting and boiling points of a material a bulk property state variable. As they cannot be controlled but still tell us about the system?
 
I would say that a state variable must be a physical quantity and not some mathematical function of it.

As for the melting and boiling point, what do you mean by <cannot be controlled> ?
 

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