Is My Acid-Base Mixture Actually Neutral?

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Discussion Overview

The discussion revolves around the neutrality of a mixture of hydrochloric acid (HCl) and sodium hydroxide (NaOH) based on pH testing using litmus paper. Participants explore the implications of their experimental observations and the potential concentrations of the solutions used.

Discussion Character

  • Experimental/applied
  • Debate/contested

Main Points Raised

  • One participant describes adding equal volumes of HCl and NaOH and observing that the solution turns blue with red litmus paper, suggesting it is basic.
  • Another participant suggests that the observed alkalinity may result from an excess of NaOH or a higher concentration of NaOH compared to HCl.
  • A third participant estimates that with a 1% accuracy in volume measurement, the pH could vary significantly, indicating a possible overshoot in the reaction.
  • A participant mentions the lack of information about the concentrations of the solutions provided by the lab teacher, leading to uncertainty about the results.
  • One participant acknowledges the potential for standard error in pipetting, which could affect the outcome of the mixture's pH.

Areas of Agreement / Disagreement

Participants express uncertainty about the concentrations of the solutions and whether the mixture is indeed neutral. There is no consensus on the exact cause of the observed pH results.

Contextual Notes

Limitations include the unknown concentrations of HCl and NaOH, potential errors in volume measurement, and the variability in pH based on the actual amounts of reagents present.

david2120
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In my chmeistry lab i use a pipet 5.0 ml of HCl and add it to a beaker. To this beaker I also added 5.0 ml NaOH. I stir the mixture and when a red litmus it turn to blue and when i put a blue litmus it stay blue. So that means its a base, but since its a mixture of an acid and a base shouldn't it be neutral? Did I do something wrong or is it correct?
 
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If your pH test are showing an alkaline solution, then you have either added too much Sodium Hydroxide or the Sodium Hydroxide is more concentrated than the Hydrochloric Acid. In my experience you never get exactly a neutral solution, you tend to go a bit too far.
 
Assuming you measured volumes with 1% accuracy (not bad) your solution may contain up to 2% excess of one of the reagents. Assuming 0.1M solutions your pH can be anywhere between 3.00 and 11.00 - looks like you have overshot :wink:
 
well my lab teacher provided the Hcl and NaOH so we don't know how concentrated it is. She only told us to use 5 ml of each and when I put the red litmus it turn blue which means its base. So from my understanding Naoh is more concentrated then HCl since they both had the same amount of ml. Am I Correct?
 
Yes, assuming of course that you added the same amount, the pipette will have a standard error associated with the volume.
 

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