Is My pH Calculation for NaOH Correct?

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Discussion Overview

The discussion revolves around the calculation of pH for sodium hydroxide (NaOH) and nitric acid (HNO3), focusing on the methods used for determining pH and pOH values, as well as the assumptions regarding dissociation in strong acids and bases.

Discussion Character

  • Technical explanation
  • Mathematical reasoning
  • Homework-related

Main Points Raised

  • One participant calculates the pH of 1x10^-2 NaOH and arrives at a pH of 12, using the relationship pH + pOH = 14.
  • Another participant confirms the calculation is correct, assuming a temperature around room temperature.
  • A third participant notes that the pH + pOH = 14 relationship is valid at 25 degrees Celsius, but questions its accuracy at other temperatures.
  • A participant inquires about calculating the pH of 1x10^-5 HNO3 and whether the method for acids is similar to that for bases.
  • One participant questions if the pH of HNO3 could be 5.
  • Another participant asserts that HNO3 is a strong acid and is 100% dissociated, implying a different expected pH.
  • A later reply agrees that a pH of 5 for HNO3 is possible.

Areas of Agreement / Disagreement

Participants generally agree on the method for calculating pH for strong acids and bases, but there is some uncertainty regarding the implications of temperature on the pH + pOH relationship and the specific pH value for HNO3.

Contextual Notes

There are assumptions regarding temperature effects on pH calculations and the complete dissociation of strong acids, which may not hold under all conditions.

Who May Find This Useful

Students and individuals interested in chemistry, particularly those learning about acid-base calculations and the properties of strong acids and bases.

omni
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i need to Calculate the pH of 1x10^-2 NaOH

so i did like this: [OH-]=10^-2

POH=-log[OH-]=-log[10^-2]=2

and if i work with the Formula :pH+POH=14 so i will get pH+2=14

so the for the 1x10^-2 NaOH the ph=12 do i correct?

thnaks.
 
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Yes, assuming its temperature is around room temperature.
 
Water ion product.

pH + pOH = 14 works perfectly well for 25 deg. Depending on the required accuracy it may be acceptable or may be not acceptable for other temperatures.
 
thanks to both of you about your answer.

and yes i speak about 25c.

i need help to Calculate the pH of 1x10^-5 of HNO3

to Calculate base as i showed here is the same way to Calculate acid like is ask now?

thanks.
 
is it possible that the ph of HNO3 is 5 ?
 
Yes, you can assume HNO3 is a strong acid, 100% dissociated.
 
yes it is possible...
 

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