Is Potassium More Reactive Than Lithium? A Look at the Electrochemical Series

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Discussion Overview

The discussion centers around the reactivity of potassium compared to lithium, particularly in the context of the electrochemical series and displacement reactions. Participants explore definitions of reactivity and the implications of standard conditions on these reactions.

Discussion Character

  • Debate/contested

Main Points Raised

  • Some participants note that the electrochemical series ranks lithium above potassium, suggesting lithium gives up electrons more easily.
  • Others assert that potassium is more reactive than lithium, prompting a request for clarification on what "more reactive" means.
  • One participant proposes that potassium will displace lithium from lithium chloride (LiCl), suggesting a practical application of reactivity.
  • A later reply questions the validity of this displacement claim, highlighting that standard potentials are based on standard conditions and that the reactivity of solids may differ from these conditions.
  • Another participant requests a reference to support the claim about potassium displacing lithium from LiCl, indicating a need for further evidence in the discussion.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the definitions of reactivity or the implications of the electrochemical series, and multiple competing views remain regarding the reactivity of potassium and lithium.

Contextual Notes

Limitations include the dependence on definitions of reactivity and the conditions under which displacement reactions are considered, as well as the unresolved nature of the claims regarding potassium displacing lithium from LiCl.

jsmith613
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The electrochemical series:
http://www.chemguide.co.uk/physical/redoxeqia/ecs.html#top
ranks Li above K
but potassium is more reactive than lithium
given that Lithium gives up electrons more easily according to the electrochemical series, how can this be?
 
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jsmith613 said:
potassium is more reactive than lithium

Define "more reactive".
 
Borek said:
Define "more reactive".

will displace it from its compound
so K will displace Li from LiCl
 
jsmith613 said:
so K will displace Li from LiCl

Will it? Even if, standard potentials are for standard conditions (activity of everything equal 1). Reacting two solids has nothing to do with standard conditions.
 
Can you provide a reference for your claim. I tried Googling it and kind find any reference to Potassium displacing Lithium from LiCl.
 

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