Is the product of two hermitian matrices always hermitian?

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The discussion centers on the Hermitian nature of the momentum operator squared, ##p^2##, and its fourth power, ##p^4##, particularly in the context of hydrogen states with azimuthal quantum number ##l=0##. It is established that while ##p^2## is Hermitian, ##p^4## is not, due to the failure of the operators to commute in this specific case. This contradiction arises from the implications of Hermiticity and the boundary terms involved in the calculations, leading to the conclusion that ##p^4 \neq (p^2)^2## under these conditions.

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  • #91
Hans de Vries said:
So, with the (correct) version of the post above we may write more general for ##P=\hat{p}_r##:

##\hat{p}_r~~=~~ i\hbar\left(\dfrac{\partial}{\partial r} +\dfrac{1}{r}\right)##

For an arbitrary power ##\hat{p}_r^n## we can write

##\hat{p}^n_r~~=~~ (i\hbar)^n\left(\dfrac{\partial}{\partial r} +\dfrac{n}{r}\right)\left(\dfrac{\partial}{\partial r}\right)^{n-1}##

or alternatively:

##\hat{p}^n_r~~=~~ (i\hbar)^n\left(\dfrac{1}{r^n}\dfrac{\partial}{\partial r}r^n\right)\left(\dfrac{\partial}{\partial r}\right)^{n-1}##
But these powers have different domains, which causes the problems discussed in the present thread.
 
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  • #92
Happiness said:
Intro to QM, David Griffiths, p269
View attachment 248344
Screen Shot 2019-08-29 at 11.54.34 AM.png
 
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  • #94
A. Neumaier said:
It is the Lebesgue integral over ##R^3##, but only if you say that ##x## denote Cartesian coordinates.
The integral is over Euclidean ##\mathbb{R}^3## and as such the volume element is independent of the choice of coordinates,
$$\mathrm{d}^3 x = \epsilon_{ijk} \partial_i \vec{x} \partial_j \vec{x} \partial_k \vec{x} \mathrm{d}^3 q.$$
Of course, it's this specific integral measure to be used in the Hilbert space, because we are dealing with a representation/realization of the Galilei group, where space is Euclidean.
 
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