In grade school, we were taught that when a hydrogen atom shares its electron with a chlorine atom, a covalent bond is formed. It holds together the new molecule, hydrogen chloride. Since this compound exists as a gas at standard conditions, it is designated by the chemical formula [tex]\inline{HCl_{(g)} }[/tex]. We also learned that when hydrogen chloride gas is dissolved in water, it becomes aqueous hydrogen chloride [tex]\inline{HCl_{(aq)} }[/tex]. The proper name for this is hydrochloric acid.
Later on, we were informed that the molecule does not remain whole once in an aqueous solution. It ionizes to form [tex]\inline{H^+_{(aq)}}[/tex] ions and [tex]\inline{Cl^-_{(aq)}}[/tex] ions. We were left with this notion, relatively unaltered, until the Bronsted-Lowry unit, where we learned that the [tex]\inline{H^+_{(aq)}}[/tex] ion actually reacts with a water molecule to form the hydronium ion: [tex]\inline{H_3O^+_{(aq)}}[/tex]. Another way of looking at it is that the water molecule accepts a proton “donation” from [tex]\inline{\HCl_{(aq)} }[/tex]. A crucial point in this unit was that a strong acid is defined as one that nearly completely dissociates (or is it ionizes?) in this manner.
Whoa! That’s the kicker. This means that the final products in the process of dissolving hydrogen chloride are almost entirely hydronium ions and chloride ions. This is the final “acidic” solution. It is the one that displays all of the empirical properties of an acid (i.e. conducts electricity, turns blue litmus red, has a pH < 7.0, etc.). These empirical properties can be attributed entirely to the hydronium ion. Put another way, in the final acidic solution, the so-called strong acid, [tex]\inline{HCl_{(aq)} }[/tex], is present in negligible quantities. So what is an acid, and how can we call [tex]\inline{HCl_{(aq)} }[/tex] an acid? Again, I emphasize that for all “strong acids”, the aqueous acidic solution is composed almost entirely of hydronium ions (and the corresponding anions). If this is true, then does the term “hydrochloric acid” really have any meaning at all?