Limiting Reagent: How Do I Determine It?

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Discussion Overview

The discussion revolves around determining the limiting reagent in a chemical reaction, specifically the reaction between zinc (Zn) and hydrochloric acid (HCl) to produce zinc chloride (ZnCl2) and hydrogen gas (H2). Participants explore the methodology for identifying the limiting reagent, including considerations of mass versus moles and the necessity of having specific amounts of reactants.

Discussion Character

  • Technical explanation, Debate/contested, Conceptual clarification

Main Points Raised

  • One participant explains their method for determining the limiting reagent based on the mass of Zn and HCl, concluding that HCl is the limiting reagent.
  • Another participant questions whether limiting reagent calculations should be done in terms of mass or moles, suggesting that knowing the moles of HCl is necessary for accurate determination.
  • A third participant emphasizes that limiting reagents can only be identified when specific amounts of reactants are provided, arguing that the concept does not apply to general statements about reactions without defined quantities.
  • A later reply acknowledges the previous points but does not add further technical content.
  • One participant expresses gratitude for the assistance received in the discussion.

Areas of Agreement / Disagreement

Participants express differing views on the conditions under which limiting reagents can be determined, with some emphasizing the need for specific quantities while others focus on the methodology of calculation. No consensus is reached regarding the correct approach to the problem.

Contextual Notes

Limitations include the lack of clarity on whether calculations should be based on mass or moles, and the necessity of having defined amounts of reactants to properly identify a limiting reagent.

Cromptu
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I have some doubts in determining the limiting reagent in a question

Based on my understanding, I will explain how I found out the limiting reagent in this problem. Please tell me if my explanation is correct or not.

Equation : Zn + 2HCl - ZnCl2 + H2

To determine the limiting reagent, we need to see how much ZnCl2 will Zn and HCl produce separately.
So,
65.4g of Zn gives 136.4g of ZnCl2
Thus 1g of Zn will give 2.08g of ZnCl2

Now,
73g of HCl gives 136.4g ZnCl2
Thus 1g of HCl will give 1.86g of ZnCl2

Now the limiting reagent is the one which produces the least amount of ZnCl2

Thus in this equation, HCl is the limiting reagent.


please tell me if my explanation is correct or not.
Please help!
 
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It has been a long time since I've done a question like this, but are limiting reagent questions to be done in terms of mass or in terms of moles? If they are in terms of moles then you have a problem because you'll need to know how many moles of 2HCl you need.
 
First of all - limiting reagent exists only if amounts of reactants are given. So if the question is "if you react 1g of Zn with 1g of HCl, which one is a limiting reagent" - you can calculate an answer. But if the question is "which is the limiting reagent if you mix Zn with HCl" - it doesn't make sense.

In other words - limiting reagent is not a "property" of the reaction.
 
Last edited:
Borek beat me to it so I leave it in his good hands.

As often here we are given an answer and have to work out what is the question; we are not too bad at it. :biggrin:
 
Thankyou so much :)
You guys rock! :D
 

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