Composition of Freezing Point Crystals in a Glacial Acetic Acid Solution

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Discussion Overview

The discussion revolves around the composition of the first crystal formed when cooling a solution of acetamide in glacial acetic acid. Participants explore the implications of freezing point depression and the nature of the mixture at the freezing point, considering whether the crystal contains only acetamide, only acetic acid, both, or neither.

Discussion Character

  • Homework-related, Conceptual clarification, Debate/contested

Main Points Raised

  • One participant asserts that the crystal should contain both acetamide and acetic acid, as it is a solution that freezes at the same temperature.
  • Another participant introduces the concept of eutectic systems, suggesting that not all mixtures behave in the same way when freezing.
  • A participant questions how to predict the composition of the crystal without additional information, such as melting points.
  • It is noted that melting points are crucial for understanding the behavior of mixtures, especially when the solute concentration is low.
  • One participant expresses dissatisfaction with the question, indicating that it may not have a straightforward answer without further context.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the composition of the crystal. There are competing views regarding the nature of the freezing process and the importance of melting points in determining the answer.

Contextual Notes

Participants highlight the lack of information regarding melting points and the assumptions about the behavior of the solution at low solute concentrations, which may affect the freezing process.

Tanishq Nandan
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Homework Statement


A solution contains 0.1mol of acetamide in 1Lit of glacial acetic acid.When the solution is cooled,the first crystal that appeared at the freezing point contains the molecules of
A.acetamide only
B.Acetic acid only
C.both acetamide and acetic acid
D.None

Homework Equations


Depression in freezing point=(molal depression constant)*(molality of solution)

The Attempt at a Solution


I don't see why there should be anything other than C.
It's a solution..consists of both solute and solvent,which have formed a composite mixture that freezes at the same temperature.So,shouldn't the crystal contain both of those components.
However,answer given is B
 
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Tanishq Nandan said:
,which have formed a composite mixture that freezes at the same temperature

That would be an eutectic system, not every mixture works this way.
 
Oo..well,then how can we predict the answer for this question?
 
Just by looking at the melting points.
 
But..that isn't given in the question...and I don't think I'm supposed to remember the melting pt of either acetamide or acetic acid..
 
On the second thought - melting point would be the most important thing for mixture in which molar fractions of both substances involved are comparable. When concentration of the solute is much lower, its activity is also very low, so it can not freeze that easily.

I don't like the question, I am not convinced the answer is easy to give without additional information.
 
Ok,thank you
 

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