Making X-Aerogel from Sodium Silicate & Polystyrene

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SUMMARY

This discussion focuses on the process of creating X-Aerogel using Sodium Silicate (water glass) and polystyrene (Styrofoam). The proposed method involves mixing Sodium Silicate with ammonia to form a sol-gel, followed by washing with acetone and incorporating polystyrene to enhance strength. The final product is expected to be 300 times stronger than regular Aerogel and capable of ambient drying using hexane, eliminating the need for supercritical drying methods. The user seeks input on the calculations for the necessary amounts of water, polystyrene, and ammonia.

PREREQUISITES
  • Understanding of sol-gel chemistry
  • Familiarity with Sodium Silicate and its properties
  • Knowledge of polymer interactions with hydroxyl groups
  • Basic skills in laboratory procedures involving solvents like acetone and hexane
NEXT STEPS
  • Research the properties and applications of X-Aerogel
  • Learn about the sol-gel process in detail
  • Investigate the effects of different solvents on Aerogel formation
  • Explore alternative methods for creating Aerogels, such as SEAgel production
USEFUL FOR

This discussion is beneficial for students, materials scientists, and hobbyists interested in aerogel production, particularly those looking for cost-effective methods and alternatives to supercritical drying.

Dr Gonzo
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I am planing to make some X-Aerogel out of Sodium Silicate (aka Water glass) and polystyrene (aka Styrofoam)

this combo will produce an Aerogel that is both cheap and can be ambiently dried with hexan without the need for Supercritically drying. Hexane is pretty cheap its one of the main ingredients in gasoline. My solvent will be acetone also cheap. The sodium silicate will be gelled with the base ammonia (also cheap.)

An X-Aerogel is an Aerogel with polymers added to increase strength about 300 times with a mass increase of *3. this also gives X Aerogel the ability to bend. how this works is the polymers attach to the hydroxyl groups on the outside of the Aerogels structure. They act as Duck tape holding the structure together.my planned procedure

1.Mix the sodium silicate with ammonia to activate the hydroxyl to form sol gel

2.wash sodium silicate gel with acetone 5 or 6 times

3.drop some Styrofoam into the acetone (should dissolve into the gel not sure on that part)

4.give the polystyrene time to bond to the hydroxyl groups on the sodium silicate

5.exchange the acetone with Hexane and let the Aerogel dry

Being about 300 times stronger then regular Aerogel it should be able to dry ambiently with the hexane without cracking or shrinking past 80% original volume.

Any input would be welcome i still haven't done any calculations on the amount of H2O, polystyrene or ammonia needed.

This may make some Ghetto Aerogel but i need to create some for a school project and
building a Supercritically dryer is out of the question.

Links
http://eetd.lbl.gov/ECS/Aerogels/sa-making.html
http://www.aerogel.org/?p=1058
http://www.aerogel.org/?p=1027
 
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Look into making SEAgel, though not as useful I am sure it would be cheaper and easier to make if you have a decent vacuum and OK temperature control. It is made by freezing an agar gel and then sublimating the ice in the a vac... This creates something even lighter then Aerogel, and you can eat it... Check it out:

When full of a lighter gas, or hot.. I think it can be even lighter then air!
 
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like the idea but my project requires me to make a chunk that can be used for a window.