Visigoth said:
Also, my intuition is failing me here: if I am moving at 99.9999999- % at the speed of light, and I begin walking forward (i.e. accelerating), is my velocity not greater than that of the vessel? Or does this have something to do with inertial frames of reference?
Your speed is only 99.999999% of c from an outside reference frame that is observing your motion.
Let's say this "stationary" reference frame is on Earth.
Relative to your reference frame (presumably, the one attached to the spacecraft moving at 99.99999% of c relative to Earth), you are (more or less) at rest, and then you begin walking forward at say 3 mph or something. It's better to imagine that you are walking in your spacecraft at a constant velocity, rather than "accelerating".. Accelerations rather mess up special relativity, which can only handle physics in inertial (i.e., non-accelerating) reference frames.
Technically speaking, in "your" reference frame, your "speed" is still zero, although in the reference frame attached to the ("moving") spaceship, your "speed" would be 3 m.p.h. Relative to the Earth-based reference frame which is observing the velocity of your spacecraft , your speed would be 99.99999% of c + 3 mph, added together using the Lorentz velocity addition formula, which result will always give you a speed smaller than c.
You could even shoot a bullet from the front of your spacecraft , which bullet moves relative to your spacecraft at 99.9999% of c. Relative to the Earth-based observer back on Earth, he'll detect that yes, the bullet is moving "faster" than the spacecraft which fired it, but no, both objects are still moving at a speed lower than c.