Mass spectrum-need 3 peak designations

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SUMMARY

The discussion focuses on identifying three specific m/z peaks at 95, 109, and 123 in a mass spectrum related to the compound bicyclo[n.o.t.]forbiddenene. The user has successfully identified other peaks but seeks assistance with these particular values. The context suggests familiarity with mass spectrometry and the identification of molecular structures based on spectral data.

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  • Understanding of mass spectrometry principles
  • Familiarity with m/z peak interpretation
  • Knowledge of organic compound structures
  • Experience with spectral analysis techniques
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  • Research the molecular structure of bicyclo[n.o.t.]forbiddenene
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Chemistry students, mass spectrometry practitioners, and researchers involved in organic compound identification will benefit from this discussion.

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Homework Statement


I am assigning m/z peaks on a mass spectrum, and there are 3 peaks not on the chart given by the instructor, and I was wondering if anyone can help me determined their identities. The peaks I am unsure of are found at 95 m/z, 109 m/z, and 123 m/z; I already figured out the rest of them. Thanks!

Homework Equations


N/A.

The Attempt at a Solution


I already determined the 4 peaks on the left and the 2 on the right, and just need help with the peaks at 95 m/z, 109 m/z, and 123 m/z.

Spectrum found at:
IMG.cgi?fname=MSNW8935&imgdir=msW.png
 
Last edited:
Physics news on Phys.org
Looks like the textbook example of bicyclo[n.o.t.]forbiddenene.
I've seen this and a closely related structure, message[4.0.4]failurene, many times in my travels on the internet...
 

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