Molecular spectroscopy and accepted literature values

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SUMMARY

The discussion centers on comparing experimental results of vibronic transitions for the N2 molecule with accepted literature values. Key parameters include vibrational frequencies and dissociation energies related to the N2 second positive and N2+ first negative band systems. The primary resource for accepted values is the book "Spectra of Diatomic Molecules" by Herzberg, along with the NIST Chemistry WebBook for more current data.

PREREQUISITES
  • Understanding of vibronic transitions in molecular spectroscopy
  • Familiarity with diatomic molecular constants
  • Knowledge of the N2 second positive and N2+ first negative band systems
  • Access to spectroscopic literature and databases
NEXT STEPS
  • Research the NIST Chemistry WebBook for updated molecular constants
  • Study the methodology for measuring vibrational frequencies in diatomic molecules
  • Explore advanced topics in molecular spectroscopy, focusing on vibronic transitions
  • Review the latest publications on N2 spectroscopy for comparative analysis
USEFUL FOR

Researchers in molecular spectroscopy, chemists studying diatomic molecules, and students conducting experiments on vibronic transitions will benefit from this discussion.

duff18
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Hi,
I have finished an experiment about vibronic transitions for the N_2 molecule and I'd like to compare my results ( vibrational frequencies and dissociation energies of the electronic states interested in the N_2 second positive and N+_2 first negative band systems ) with the accepted literature values.

Does anyone know where I can find these accepted values ?
 
Physics news on Phys.org
I've found them, just in case someone else will be interested: vibrational and rotational constants of diatomic molecules can be found in Herzberg - Spectra of diatomic molecules
 

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