Momentum operator in the position representation

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Discussion Overview

The discussion revolves around the calculation of the momentum operator $\widehat{\vec{P}}$ in the position representation as presented in the book "Quantum Mechanics" by Nouredine Zettili. Participants are trying to understand the mathematical steps involved in the derivation and the implications of certain definitions and notations in quantum mechanics.

Discussion Character

  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants express confusion about the transition from the first to the second line in the calculation of $\langle \vec{r} | \widehat{\vec{P}} | \psi \rangle$, particularly regarding the application of the identity operator and the definitions of the momentum operator and the position representation.
  • One participant attempts to clarify the use of the identity operator $| \vec{p} \rangle \langle \vec{p} | = \widehat{I}$ and how it relates to the calculation, suggesting that the momentum operator acts on the identity operator to yield the desired result.
  • Another participant questions the interpretation of the relation $\vec{P} | \vec{p} \rangle = \vec{p} | \vec{p} \rangle$, noting that it seems to imply that the vector $\vec{p}$ is an eigenvalue, which traditionally is a numerical concept.
  • Responses clarify that in quantum mechanics, the notation can be non-standard, and that $\vec{p}$ is indeed treated as an eigenvalue associated with the eigenstate $| \vec{p} \rangle$.
  • One participant shares their background in mathematics and expresses a desire to adapt to the conventions of quantum mechanics as they prepare for a master's program in mathematical physics.

Areas of Agreement / Disagreement

Participants generally agree on the steps of the calculation but express differing interpretations of the notation and concepts, particularly regarding eigenvalues in quantum mechanics. The discussion remains unresolved regarding the clarity of these concepts.

Contextual Notes

There are limitations in the discussion related to the interpretation of eigenvalues as vectors versus numbers, and the notation used in quantum mechanics may not align with traditional mathematical definitions.

Who May Find This Useful

This discussion may be useful for students and self-learners in quantum mechanics, particularly those with a mathematical background seeking to understand the nuances of quantum notation and operator theory.

Fantini
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Hi! :) I'm trying to understand the following calculation. The book Quantum Mechanics by Nouredine Zettili wants to determine the form of the momentum operator $\widehat{\vec{P}}$ in the position representation. To do so he calculates as follows: $$\begin{aligned}
\langle \vec{r} | \widehat{\vec{P}} | \psi \rangle & = \int \langle \vec{r} | \widehat{\vec{P}} | \psi \rangle \langle \vec{p} | \psi \rangle \, d^3 p \\
& = \int \vec{p} \langle \vec{r} | \vec{p} \rangle \langle \vec{p} | \psi \rangle \, d^3 p \\
& = \frac{1}{(2 \pi \hbar)^{3/2}} \int \vec{p} \exp \left( \frac{i \vec{p} \cdot \vec{r} }{\hbar} \right) \Psi(\vec{p}) \, d^3 p.
\end{aligned}$$ The momentum operator is defined as $\widehat{\vec{P}} | \vec{p} \rangle = \vec{p} | \vec{p} \rangle$.

I don't understand he's doing from the first to the second line, after applying the definition of $\langle \vec{r} | \widehat{\vec{P}} | \psi \rangle$. I know that $$\langle \vec{r} | \vec{p} \rangle = \frac{1}{(2 \pi \hbar)^{3/2}} \exp \left( \frac{i \vec{p} \cdot \vec{r}}{\hbar} \right)$$ and $$\langle \vec{p} | \psi \rangle = \Psi(\vec{p}),$$ but I don't see how he gets to that. The book claims to use that $ | \vec{p} \rangle \langle \vec{p} | = \widehat{I}$, the identity operator, and $\langle \vec{r} | \vec{p} \rangle = \ldots$.

Here's what I thought: if we use that $ | \vec{p} \rangle \langle \vec{p} | = \widehat{I}$ then $$\begin{aligned} \langle \vec{r} | \widehat{\vec{P}} | \vec{p} \rangle \langle \vec{p} | \psi \rangle & = \langle \vec{r} | \widehat{\vec{P}} \widehat{I} | \psi \rangle \\ & = \langle \vec{r} | \widehat{\vec{P}} | \psi \rangle \\ & = \langle \vec{r} | \vec{p} | \vec{p} \rangle | \psi \rangle \\ & = \vec{p} \langle \vec{r} | \vec{p} \rangle | \psi \rangle. \end{aligned}$$ That doesn't seem to be what's happening. If we don't use that $ | \vec{p} \rangle \langle \vec{p} | = \widehat{I}$, then I find an extra $| \vec{p} \rangle$ lying around.

Where am I going wrong?
 
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Fantini said:
Hi! :) I'm trying to understand the following calculation. The book Quantum Mechanics by Nouredine Zettili wants to determine the form of the momentum operator $\widehat{\vec{P}}$ in the position representation. To do so he calculates as follows: $$\begin{aligned}
\langle \vec{r} | \widehat{\vec{P}} | \psi \rangle & = \int \langle \vec{r} | \widehat{\vec{P}} | \psi \rangle \langle \vec{p} | \psi \rangle \, d^3 p \\
& = \int \vec{p} \langle \vec{r} | \vec{p} \rangle \langle \vec{p} | \psi \rangle \, d^3 p \\
& = \frac{1}{(2 \pi \hbar)^{3/2}} \int \vec{p} \exp \left( \frac{i \vec{p} \cdot \vec{r} }{\hbar} \right) \Psi(\vec{p}) \, d^3 p.
\end{aligned}$$ The momentum operator is defined as $\widehat{\vec{P}} | \vec{p} \rangle = \vec{p} | \vec{p} \rangle$.

I don't understand he's doing from the first to the second line, after applying the definition of $\langle \vec{r} | \widehat{\vec{P}} | \psi \rangle$. I know that $$\langle \vec{r} | \vec{p} \rangle = \frac{1}{(2 \pi \hbar)^{3/2}} \exp \left( \frac{i \vec{p} \cdot \vec{r}}{\hbar} \right)$$ and $$\langle \vec{p} | \psi \rangle = \Psi(\vec{p}),$$ but I don't see how he gets to that. The book claims to use that $ | \vec{p} \rangle \langle \vec{p} | = \widehat{I}$, the identity operator, and $\langle \vec{r} | \vec{p} \rangle = \ldots$.

Here's what I thought: if we use that $ | \vec{p} \rangle \langle \vec{p} | = \widehat{I}$ then $$\begin{aligned} \langle \vec{r} | \widehat{\vec{P}} | \vec{p} \rangle \langle \vec{p} | \psi \rangle & = \langle \vec{r} | \widehat{\vec{P}} \widehat{I} | \psi \rangle \\ & = \langle \vec{r} | \widehat{\vec{P}} | \psi \rangle \\ & = \langle \vec{r} | \vec{p} | \vec{p} \rangle | \psi \rangle \\ & = \vec{p} \langle \vec{r} | \vec{p} \rangle | \psi \rangle. \end{aligned}$$ That doesn't seem to be what's happening. If we don't use that $ | \vec{p} \rangle \langle \vec{p} | = \widehat{I}$, then I find an extra $| \vec{p} \rangle$ lying around.

Where am I going wrong?
Sorry it's taken me so long to respond. A visit to my parents, two week long flus, and a 3 day anxiety attack pretty much fills up a month.

Anyway, where did you get that first line from? Maybe it's right but to me it doesn't even look wrong. Also [math]I = \int | \vec{p} > < \vec{p} |~d^3 \vec{p}[/math]

Let's take it step by step.
[math]< \vec{r} | \vec{P} | \psi > ~ = ~ < \vec{r} | \vec{P} I | \psi >[/math]

[math]= < \vec{r} | \vec{P} \int | \vec{p} > < \vec{p} | d^3 \vec{p} ~ | \psi >[/math]

[math]= \int < \vec{r} | \vec{P} | \vec{p} > < \vec{p} | \psi > ~d^3 \vec{p}[/math]

[math]= \int \vec{p} < \vec{r} | \vec{p} > < \vec{p} | \psi > ~d^3 \vec{p}[/math]

[math]= \frac{1}{(2 \pi \hbar)^{3/2}} \int \vec{p} \psi( \vec{p} ) e^{i p \cdot r/ \hbar} ~d^3 \vec{p}[/math]

-Dan
 
Thank you for answering, topsquark!

I think I understand everything. You write $\vec{P} = \vec{P}\cdot \widehat{I}$ and uses that $$\widehat{I} = \int |\vec{p} \rangle \langle \vec{p} | \, d^3 p.$$ Then you pass the ket $| \psi \rangle$ inside the integral and pair it up with the bra $\langle p |$, forming $\psi(\vec{p})$. Next you do the same with $\langle \vec{r} | \vec{P}$ and apply the definition of $\vec{P} | \vec{p} \rangle = \vec{p} | \vec{p} \rangle$, pair up $\langle \vec{r} | \vec{p} \rangle$ and the rest follows through.

One question: the relation $\vec{P} | \vec{p} \rangle = \vec{p} | \vec{p} \rangle$ makes no sense for me at all. I read this as if he's saying the vector $\vec{p}$ is an eigenvalue associated to the vector $| \vec{p} \rangle$, but eigenvalues are numbers, not vectors! :confused: Can you shed some light on this?
 
Fantini said:
Thank you for answering, topsquark!

I think I understand everything. You write $\vec{P} = \vec{P}\cdot \widehat{I}$ and uses that $$\widehat{I} = \int |\vec{p} \rangle \langle \vec{p} | \, d^3 p.$$ Then you pass the ket $| \psi \rangle$ inside the integral and pair it up with the bra $\langle p |$, forming $\psi(\vec{p})$. Next you do the same with $\langle \vec{r} | \vec{P}$ and apply the definition of $\vec{P} | \vec{p} \rangle = \vec{p} | \vec{p} \rangle$, pair up $\langle \vec{r} | \vec{p} \rangle$ and the rest follows through.

One question: the relation $\vec{P} | \vec{p} \rangle = \vec{p} | \vec{p} \rangle$ makes no sense for me at all. I read this as if he's saying the vector $\vec{p}$ is an eigenvalue associated to the vector $| \vec{p} \rangle$, but eigenvalues are numbers, not vectors! :confused: Can you shed some light on this?
Good notation is not what Quantum Mechanics is famous for.
[math]\vec{P} | \vec{p} > = \vec{p} | \vec{p} >[/math]

[math]| \vec{p} > [/math] is the eigenstate (eigenvector, eigenket, whatever) that "carries" the eigenvalue [math]\vec{p}[/math].

[math]\vec{P}[/math] is the (Hermitian) operator that returns the momentum of the eigenvector [math]| \vec{p} >[/math]. [math]\widehat{P}[/math] is another common symbol for this operator.

So letting the operator [math]\vec{P}[/math] act on [math]| \vec{p} > [/math] gives [math]\vec{P} | \vec{p} > = \vec{p} | \vec{p} > [/math]. And because [math]\vec{P}[/math] is Hermitian we also have [math]< \vec{p} | \vec{P} = < \vec{p} | \vec{p} [/math].

I'm using the symbols that I was taught. You need to make sure you know the terminology that your instructor is using. Please let me know if you have trouble understanding notation and I'll be happy to explain it out to you.

-Dan
 
That seems standard to me. It's just that my mathematician-trained mind sees eigenvalues as numbers, not vectors. :confused: I'll get used to it, I guess. I'm self-studying this. I want to apply for a masters in mathematical physics in a physics institute. To get funding I need to do well in a test consisting of 10 questions, divided in 2 questions of classical mechanics, 2 questions of electromagnetism, 2 questions of quantum mechanics, 2 questions of modern physics and 2 questions of thermodynamics and statistical mechanics.

I'm self-teaching myself three (QM, TSM and MP), while I had one course in CM and EM each.

But I understand your reasoning perfectly. Thanks! :)
 
Fantini said:
That seems standard to me. It's just that my mathematician-trained mind sees eigenvalues as numbers, not vectors. :confused: I'll get used to it, I guess. I'm self-studying this. I want to apply for a masters in mathematical physics in a physics institute. To get funding I need to do well in a test consisting of 10 questions, divided in 2 questions of classical mechanics, 2 questions of electromagnetism, 2 questions of quantum mechanics, 2 questions of modern physics and 2 questions of thermodynamics and statistical mechanics.

I'm self-teaching myself three (QM, TSM and MP), while I had one course in CM and EM each.

But I understand your reasoning perfectly. Thanks! :)
If it makes you feel any better look at it this way: We have three operators [math]P_x \text{, } P_y \text{, and } P_z[/math]

Acting on a ket [math]| \vec{p} > [/math] we get [math]P_x = p_x | \vec{p} > [/math], etc. where [math]p_x[/math] is the x component of the momentum.

-Dan
 

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