Naming an Ionic compound from its Formula

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Discussion Overview

The discussion revolves around the naming of ionic compounds from their chemical formulas, specifically focusing on the compounds CaO and PbCrO4. Participants explore the definitions of oxoanions and the naming conventions associated with them, addressing both theoretical and practical aspects of chemical nomenclature.

Discussion Character

  • Homework-related
  • Debate/contested
  • Technical explanation

Main Points Raised

  • One participant states that the book indicates the naming convention for oxoanions, suggesting that CaO should be named calcite instead of calcium oxide.
  • Another participant clarifies that CaO is not an oxoanion and points out that calcite refers to calcium carbonate, not calcium oxide.
  • A participant questions why CaO is not considered an oxoanion, noting its composition of oxygen and a negative charge.
  • It is asserted that CaO has no charge, implying it does not fit the criteria for an oxoanion.
  • A participant introduces a different compound, PbCrO4, and questions its naming as lead(II) chromate, suggesting it should be lead chromium oxide instead.
  • Another participant explains that PbCrO4 is a salt composed of lead(II) and the chromate anion, which is indeed an oxyanion, contrasting it with CaO.
  • Clarification is provided that the presence of two metals in PbCrO4 indicates it is not a simple oxide, unlike CaO.

Areas of Agreement / Disagreement

Participants express disagreement regarding the classification of CaO as an oxoanion and the naming conventions for both CaO and PbCrO4. The discussion remains unresolved as participants hold differing views on the definitions and applications of chemical nomenclature.

Contextual Notes

There are limitations in the discussion regarding the definitions of oxoanions and the specific naming conventions applied to different types of compounds. The participants do not reach a consensus on these points.

BrainMan
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Homework Statement


Write the name of the following compound CaO


Homework Equations





The Attempt at a Solution


My book says that for oxoanions the ion with the greatest number of oxygen atoms has the suffix -ate and the one with the least amount of oxygen atoms has the suffix -ite. The books answer was calcium oxide but shouldn't the answer be calcite?
 
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This is not an oxoanion.

Besides, it happens that calcite is a (historical) name of mineral - calcium carbonate.
 
Borek said:
This is not an oxoanion.

Besides, it happens that calcite is a (historical) name of mineral - calcium carbonate.

Why is it not an oxoanion? It has oxygen and a negative charge
 
CaO has no charge.
 
Borek said:
CaO has no charge.
Ok there is another part of the problem and it is name the following compound PbCrO4. It says the answer is lead(2) chromate. Why would it be this answer because this shouldn't be a oxyanion either? Why wouldn't it be lead chromium oxide?
 
Last edited:
This is a completely different compound - and it is a salt, made of lead(II) (Pb2+) and chromate anion (CrO2-). CrO2- is an oxyanion (and has a charge, which in a compound is neutralized by the opposite charge of lead, yielding PbCrO4).

Note that the first compound contained only one metal (Ca) combined with oxygen, the latter contains two metals (Pb and Cr) - that's a strong hint it is not a simple oxide.
 
Borek said:
This is a completely different compound - and it is a salt, made of lead(II) (Pb2+) and chromate anion (CrO2-). CrO2- is an oxyanion (and has a charge, which in a compound is neutralized by the opposite charge of lead, yielding PbCrO4).

Note that the first compound contained only one metal (Ca) combined with oxygen, the latter contains two metals (Pb and Cr) - that's a strong hint it is not a simple oxide.

Ok I see thanks!
 

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