What is the format for ionic lewis structure w/ resonance?

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SUMMARY

The discussion focuses on drawing the ionic compound NH4NO2, specifically addressing the Lewis structure for the NO2- ion, which exhibits resonance. The NH4 ion is straightforward, featuring one nitrogen atom surrounded by four hydrogen atoms. The NO2- ion consists of one nitrogen atom bonded to two oxygen atoms, with resonance indicated by alternating double bonds. Participants suggest using dashed lines to represent resonance and recommend selecting one resonance structure to depict while acknowledging the existence of others.

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  • Understanding of ionic compounds and their structures
  • Familiarity with Lewis dot structures
  • Knowledge of resonance in molecular structures
  • Basic grasp of valence electrons and bonding
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  • Research how to draw resonance structures for polyatomic ions
  • Learn about the historical context of Lewis structures and resonance
  • Explore the use of dashed lines in representing resonance in chemical structures
  • Study the properties and behavior of ionic compounds in solution
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Chemistry students, educators, and anyone interested in understanding ionic compounds and resonance structures in molecular chemistry.

needingtoknow
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Homework Statement



I need to draw NH4NO2 which is an ionic compound.

3. The Attempt at a Solution

NH4 is fairly straightforward to draw, with one N in the middle and four H surrounding, and no lone pairs. The problem comes with NO2- which is one nitrogen bonded to two oxygens. However, one of the bonds is a double bond which alternates back and forth between the two oxygens (I know this is a simplified way of explaining but it is just makes it easier to explain what I have so far). There is a lone pair on the nitrogen and 6 electrons around the oxygen that only has a single bond to the nitrogen while there is only 4 electrons around the oxygen that has the double bond with the nitrogen. I have never seen an example before of an ionic lewis structure where one of the ions is a resonance structure AND also with all of the electrons on the atoms shown as well and I was wondering if there is a certain way to draw this sort of structure or do I just place the 2 resonance structures next to the NH4? Thank you
 
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needingtoknow said:

Homework Statement



I need to draw NH4NO2 which is an ionic compound.

3. The Attempt at a Solution

NH4 is fairly straightforward to draw, with one N in the middle and four H surrounding, and no lone pairs. The problem comes with NO2- which is one nitrogen bonded to two oxygens. However, one of the bonds is a double bond which alternates back and forth between the two oxygens (I know this is a simplified way of explaining but it is just makes it easier to explain what I have so far). There is a lone pair on the nitrogen and 6 electrons around the oxygen that only has a single bond to the nitrogen while there is only 4 electrons around the oxygen that has the double bond with the nitrogen. I have never seen an example before of an ionic lewis structure where one of the ions is a resonance structure AND also with all of the electrons on the atoms shown as well and I was wondering if there is a certain way to draw this sort of structure or do I just place the 2 resonance structures next to the NH4? Thank you

You will sometimes see resonance indicated with dashed/dotted lines for the second bonds.

I think that the original Lewis dot structures did not include the idea of resonance structures, so if you want to be true to G. N. Lewis, you could simply pick one to show, maybe with a note that you know that there are resonance structures.

It is interesting to look at the original paper that outlined the dot structure picture. It is from 1916, which is not that long ago. The paper includes some discussions of the idea of a cubical atom (trying to make sense of the 8 valence for many elements).
http://scarc.library.oregonstate.edu/coll/pauling/bond/papers/corr216.3-lewispub-19160400.html

I like the scanned image above, because this particular reprint of the paper belonged to Linus Pauling!
 
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