An orientation of a simplex may be thought of as an ordering of its vertices and is usually symbolized by a k-tuple, ##< σ_{j_{1}}, ... σ_{j_{k}}>##.
For instance for a 2-simplex, ##< σ_{0},σ_{1},σ_{2}>## and ##< σ_{1},σ_{2},σ_{0}>## are possible orientations.
Just as with orientation of space, two k-tuples are said to determine the same orientation of they differ by an even permutation of the vertices. and the opposite orientation if they differ by an odd permutation. For instance, the two orientations of the two simplex above are the same.
Oriented simplices are just symbols and as such one can think of the formal free abelian group generated by them. This group is completely formal.
More generally whenever one has a collection of symbols, one can think of the free abelian group that they generate. This group is just all formal finite integer linear combinations of the symbols with the requirement that the symbols must commute and that multiplication by integers is associative.
So if a and b are symbols then one says that na + mb is the same as the symbol, mb + na
and (n+m)a is the same as na + ma. One also says that 0a is the same as 0b and denote this as 0.
With simplices one treats opposite orientations as the negatives of each other in the chain group.
For instance,
## <σ_{0},σ_{1},σ_{2}> = - <σ_{1},σ_{0},σ_{2}>## and so their sum is equal to zero.The boundary operator
The boundary of an oriented k-simplex is defined to be a signed sum of the oriented simplices that are obtained by removing one vertex at a time. These are oriented faces of ##<σ>##.
I have seen two ways of defining the boundary.
One way is to take the alternating sum of the oriented k-1 faces by removing one vertex at a time sequentially..
For instance,
##∂ <σ_{0},σ_{1},σ_{2}> = <σ_{1},σ_{2}> - <σ_{0},σ_{2}> + <σ_{0},σ_{1}>##
The other way is to preassign orientations to each simplex and then define an "incidence number" that lines the boundary simplices up in the right way.
I am not sure which method your book uses.