On the quantum theory of radiation

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SUMMARY

The discussion focuses on Einstein's "On the quantum theory of radiation," specifically the derivation of equations (8) and (9) from (7) and Wien's displacement law. A_B clarifies that constants A and B are dependent on the energy states εm and εn, and emphasizes that they cannot vary with temperature T. The relationship established by Wien's Law indicates that the ratio A/B is a function of frequency ν, leading to the conclusion that A/B is proportional to ν³, thereby validating equations (8) and (9).

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A_B
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Hi,

In section 3 of Einstein's "On the quantum theory of radiation" Einstein says equations (8) and (9) follow from (7) and Wien's displacement law. I don't see how that is. For example, if we replace (8) by
<br /> \frac{A_m^n}{B_m^n} = \alpha \frac{\nu}{T} \nu^3<br />
All conditions still seem to hold. What am I missing?

Also, can somebody point me to a derivation of Wien's displacement law that does not assume Planck's formula?


Thank you,

A_B
 
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He says A and B are constants which are "characteristic for the combination of indices considered". The indices referred to are εm and εn, the initial and final energy of the state, and in particular the energy difference εm - εn, that is, the frequency ν of the emitted radiation. They cannot depend on the temperature T. So the numerator A/B must be a function of ν only, and from Wien's Law it must be proportional to ν3, giving us Eq 8.

Likewise from Wien's Law the denominator must be a function of ν/T, which implies Eq 9.
 

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