Order of acidity for oxoacids of P: H3PO4 > H3PO3 > H3PO2

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SUMMARY

The order of acidity for the oxoacids of phosphorus is established as H3PO4 > H3PO3 > H3PO2. This conclusion is based on the number of replaceable hydrogen ions (H+) and the electron-withdrawing effects of oxygen atoms in the molecular structure. While initial reasoning suggested H3PO4 was the most acidic due to its basicity, further analysis indicated that the acidity order is influenced by the presence of oxygen and the corresponding Ka values, which were referenced but not provided in the exam context.

PREREQUISITES
  • Understanding of oxoacid structures and their acidity
  • Knowledge of the concept of Ka values in acid-base chemistry
  • Familiarity with electron-withdrawing effects of functional groups
  • Basic principles of hydrogen ion (H+) replacement in acids
NEXT STEPS
  • Research the Ka values for H3PO4, H3PO3, and H3PO2 to understand their relative acidity
  • Study the impact of electronegativity and resonance on acid strength
  • Explore the role of oxygen in acid-base chemistry, particularly in oxoacids
  • Review theoretical approaches to predicting acidity without empirical data
USEFUL FOR

Chemistry students, educators, and anyone studying acid-base reactions, particularly in the context of phosphorus oxoacids.

zorro
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Homework Statement



What is the order of acidity of H3PO3, H3PO2 and H3PO4?

The Attempt at a Solution



H3PO4 must be most acidic because its basicity is highest. Greater the no. of repleacable H+, greater will be its acidity. On similar reasoning, H3PO2 is least acidic.

Is it right?
 
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There is a rule about acid strength and amount of oxygen in the molecule.
 
I guess you are talking about the withdrawing effect of Oxygens.
There is only one Oxygen doubly bonded to Phosphorus which withdraws electron density of the O-H group facilitating the release of H+. Since there is only one such O in every molecule given, I don't think we can compare based on that rule. Correct me if I am wrong.
 
Last edited:
Good point, my mistake.

Safest approach it to check tables for Ka values.
 
I googled their Ka values and to my surprise, found that the acidity order is opposite to that I mentioned in O.P.

Unfortunately these values are not given in my exam and I need an answer theoretically ( I am not so good at by-hearting things :biggrin:)
 

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