Order of Reaction from Halflife times

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SUMMARY

The reaction in question is determined to be second order based on the provided half-lives of 34 minutes and 68 minutes. The first half-life of 34 minutes indicates that the concentration falls to half its initial value, while the second half-life of 68 minutes represents a quarter-life, not a true half-life. The confusion arises from the interpretation of the timing of these half-lives, but the correct conclusion is that the reaction follows second-order kinetics as the half-life increases with decreasing concentration.

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JwdePhysics
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Homework Statement


A -> Products
The two half-lives are 34 minutes and 68 minutes respectively. Find the order of the reaction.

So I and my friends are having disagreements over whether this is first order or second order or not.

Homework Equations


For first order half-life, t = 0.693/k
For second order half-life, t = 1/([A]0k)

The Attempt at a Solution


I say it's first order because the first half life occurs at 34 minutes. Then the second half life occurs at 68 minutes (34 minutes after the first half-life). Therefore the half-life doesn't change and you would have a first-order half-life

My friends say it's second order because they interpret the problem as the second half-life occurring 68 minutes after the first half-life. And so if that were true, the half-life would double in time according to the second order half-life equation ([A]0 would get cut in half from the first half life, doubling the entire right side of the equation and therefore doubling the time).

Who is right?
 
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Looks like it is more about ambiguity and poor wording than about chemistry.
 
Strictly speaking, the answer is second order. If the concentration has fallen to half the initial value after t1, and to a quarter after t2 (from the start), then the first half life is t1 and the second half life is (t2-t1). t2 is not a half life, but a quarter-life. So your friend is right, but I'm not sure the framer of the question was using language so precisely. I must admit I assumed it was first order on first reading the question.
(On a pedantic point of style, the half life is a length of time, not a point in time. So the first half life is 34 minutes, it does not "occur at" t = 34 minutes. This may be aiding the confusion.)
 

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