Just to make it easier to talk about, let's focus on the specific case of finding the PFD of ##\frac{1}{x(x-1)}##. The first step of the problem would dictate assuming the existence of constants ##A## and ##B## such that $$\frac{1}{x(x-1)}=\frac{A}{x}+\frac{B}{x-1}$$ for all ##x## in the domain of the original expression (i.e. ##x\neq 0,1##). As a typical student of calculus, you're kinda meant to take that part as a fact whose explanation is beyond the scope of the course. The only good explanation that I'm aware of is based on concepts from a branch of math called Abstract Algebra, a topic studied by a very small percentage of the students who learn PFD. The rest of the explanation, however, is very accessible to a calculus student learning PFD as a strategy for finding antiderivatives of rational functions.
For ##x\neq 0,1##, the previous equation is equivalent to $$1=A(x-1)+Bx$$ Since this equation is true for all ##x\neq 0,1##, $$1=\lim_{x\rightarrow 0}\big(A(x-1)+Bx\big)$$ and $$1=\lim_{x\rightarrow 1}\big(A(x-1)+Bx\big)$$
I'll leave it to you to fill in the rest and convince yourself why the "root-substitution method" for finding the coefficients in a PFD problem is valid in the general case.