What is Pauli's Exclusion Principle and How Does It Apply to Fermions?

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SUMMARY

Pauli's Exclusion Principle states that no two identical fermions, such as electrons, can occupy the same quantum state simultaneously. This principle is crucial for the structure of the periodic table, as it dictates that electrons fill discrete atomic states based on quantum numbers, preventing them from sharing states within the same valence shell. The discussion also highlights the role of fermionic creation and annihilation operators, which utilize anti-commutators to enforce this principle mathematically, ensuring that states cannot be doubly occupied.

PREREQUISITES
  • Understanding of quantum mechanics and atomic structure
  • Familiarity with fermions and their properties
  • Knowledge of quantum numbers and their significance in atomic states
  • Basic comprehension of creation and annihilation operators in quantum field theory
NEXT STEPS
  • Study the implications of Pauli's Exclusion Principle in atomic theory
  • Learn about fermionic creation and annihilation operators in quantum field theory
  • Explore the concept of quantum states and their labeling using quantum numbers
  • Investigate the relationship between fermions and the periodic table of elements
USEFUL FOR

Students and professionals in physics, particularly those focusing on quantum mechanics, atomic theory, and particle physics, will benefit from this discussion.

Gravitonion
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I know the principle says that no two fermions canNot have the same atomic number, but could you explain that in detail?
 
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It means two identical fermions (say, any two electrons) cannot be in exactly the same state. So if you have a discrete way of labeling the states, say by atomic quantum numbers, then you can only have one electron in each of those states (or two if you are not counting the spin in the quantum numbers). One reason this is really important is that it gives us the periodic table-- atoms get a lot larger when you "break into a new valence shell" as you add electrons, and that's only because the new electrons can't go into the states that the previous electrons are already in.
 
Gravitonion said:
I know the principle says that no two fermions canNot have the same atomic number, but could you explain that in detail?
Are you familiar with the harmonic oscillator?

Fermionic creation and annihilation operators are constructed using anti-commutators (instead of commutators

\{b_s,b^\dagger_{s^\prime}\} = \delta_{s\,s^\prime}

\{b_s,b_{s^\prime}\} = \{b^\dagger_s,b^\dagger_{s^\prime}\} = 0

The last equation is important b/c for s=s' it can be rewritten as :

(b^\dagger_s)^2 = 0

s,s' represent the quantum numbers

You can construct a states where each s, s', s'', ... is occupied by either zero or one particle. But if you want to construct a state with two particles sitting in state s you get

|2s\rangle = (b^\dagger_s)^2|0\rangle = 0

due to the anticommutator.
 
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They can be in the same state as long as they have different positions though right?
 
Runner 1 said:
They can be in the same state as long as they have different positions though right?
Sorry, I forgot to explain that creation and annihilation operators act in momentum space and that this means that s is a collection of momentum, spin, isospin, etc.}. Therefore they are not located anywhere in position space.
 

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