Position and Momentum Operator Matrices

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SUMMARY

The discussion focuses on calculating the matrix representations of the position and momentum operators, Q and P, using the energy eigenfunctions of a one-dimensional infinite square well as a basis. The energy eigenvalues are defined by the equation E_n = (π²ħ²/2Ma²)n², with eigenfunctions given by ψ_n(x) = √(2/a) sin(nπ/a * x). The position operator Q is represented as a diagonal matrix with elements corresponding to the position values x_n along the diagonal, specifically Q = diag(x_1, x_2, ..., x_n). The discussion emphasizes the need to apply the matrix element formula A_{ij} = ⟨v_i|A|v_j⟩ to derive the matrix elements of the position operator in the eigenbasis.

PREREQUISITES
  • Understanding of quantum mechanics principles, particularly the infinite square well model.
  • Familiarity with matrix representation of operators in quantum mechanics.
  • Knowledge of eigenvalues and eigenfunctions in quantum systems.
  • Proficiency in linear algebra, specifically matrix operations and diagonalization.
NEXT STEPS
  • Study the derivation of energy eigenvalues and eigenfunctions for the one-dimensional infinite square well.
  • Learn about the matrix representation of the momentum operator P in quantum mechanics.
  • Explore the application of the completeness relation in quantum mechanics, specifically ∫|x⟩⟨x|dx = I.
  • Investigate the implications of operator matrices in quantum mechanics, focusing on their physical interpretations.
USEFUL FOR

Students and professionals in quantum mechanics, particularly those studying operator theory and matrix mechanics, as well as educators looking to enhance their understanding of quantum systems and their mathematical representations.

kreil
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Homework Statement


Find the energy eigenvalues and eigenfunctions for the one-dimensional infinite square well. Calculate the matrices for the position and momentum operators, Q and P, using these eigenfunctions as a basis.

Homework Equations


The energy eigenvalues are

E_n = \frac{\pi^2 \hbar^2}{2Ma^2}n^2

and the eigenfunctions are,

\psi_n(x) = \sqrt{\frac{2}{a}} sin \left ( \frac{n \pi}{a} x \right )

The Attempt at a Solution



Finding the energy eigenvalues and eigenfunctions is straightforward. What is really confusing me is how to use the eigenfunctions as a basis to find the matrix representations of these operators. This is problem 4.2 in Ballentine's Quantum Mechanics, and I can't find any useful information in the chapter for doing this sort of problem. Here is the best attempt I have:

The position operator Q satisfies,

\hat Q \psi_n(x) = x_n \psi_n(x)

If we represent \psi as a column matrix, we can write:

\psi_n(x) = \left[ \begin{array}{c} \psi_1(x) \\ \psi_2(x) \\ \vdots \\ \psi_n(x) \end{array} \right]

Using this representation,

\hat Q \left[ \begin{array}{c} \psi_1(x) \\ \psi_2(x) \\ \vdots \\ \psi_n(x) \end{array} \right] = \left[ \begin{array}{c} x_1 \psi_1(x) \\ x_2 \psi_2(x) \\ \vdots \\ x_n \psi_n(x) \end{array} \right]= \left[ \begin{array}{cccc} x_1 & 0 & \hdots & 0\\ 0 & x_2 & 0 \hdots & 0 \\ \vdots & \vdots & \ddots & \vdots \\ 0 & 0 & 0 & x_n \end{array} \right] \left[ \begin{array}{c} \psi_1(x) \\ \psi_2(x) \\ \vdots \\ \psi_n(x) \end{array} \right]

So Q would be this matrix with the x's along the diagonal:

\hat Q = \left[ \begin{array}{cccc} x_1 & 0 & \hdots & 0\\ 0 & x_2 & 0 \hdots & 0 \\ \vdots & \vdots & \ddots & \vdots \\ 0 & 0 & 0 & x_n \end{array} \right]

I feel like the answer is supposed to be more specific than this
 
Last edited:
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kreil said:
The position operator Q satisfies,

\hat Q \psi_n(x) = x_n \psi_n(x)

If you are talking about a one-dimensional harmonic oscillator, what the heck is x_n supposed to mean? In one dimension, \hat{Q}\psi_n(x)=x\psi_n(x).

The elements of a matrix A in a basis |v_i\rangle are given by

A_{ij}= \langle v_i|A|v_j\rangle

Apply that to find the matrix elements of the position operator in the \psi_n\rangle eigenbasis (Hint: \psi_n(x)=\langle x|\psi_n\rangle and \int |x\rangle\langle x|dx = \hat{1} ).
 

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