Qsp Calculation for NaCl+AgNO3: Determine Precipitate

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SUMMARY

The discussion focuses on calculating the solubility product constant (Qsp) for the precipitation of silver chloride (AgCl) when mixing sodium chloride (NaCl) and silver nitrate (AgNO3) solutions. The correct net ionic equation for the reaction is Cl- + Ag+ → AgCl, which indicates that the coefficients from this equation should be used to calculate Qsp. The participants clarify that the ion concentrations before and after mixing are [Ag+] = 0.00050 M and [Cl-] = 0.00250 M, leading to Qsp = (0.00050)(0.00250).

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pmahesh107
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Calculate the ion product to determine if a precipitate will form when 125 mL .00500 M sodium chloride is mixed with 125 mL .00100 M silver nitrate solution.

NaCl + AgNO3 -> NaNO3 + AgCl

Net ionic equation = 2AgCl -> 2Ag + Cl2


[Ag+] before = .00100 after = .00050
[Cl-] before = .00500 after = .00250

My question was about the Qsp. Would the Qsp = (.00050)(.00250) or Qsp = (.00050)^2(.00250) I don't understand which co-efficients to look at, the one in the equation or the one in the net-ionic equation. Thanks in advance for the help.
 
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Your question is very confusing.
The 1st and 2nd equation are different...as well flipped in a way...

you are saying one of the products is Chlorine gas... and the reactant is AgCl, which is a product of the first equation.
the netionic eq qould be Cl(-) + Ag(+) --> AgCl, and i don't know why you are trying to balance it out.
Remember its a solution, so you can have Cl(-) ions by themselves.

Are you trying to find the reaction quotient??
 
pmahesh107 said:
Net ionic equation = 2AgCl -> 2Ag + Cl2

It is not a correct net ionic equation for this reaction. If you mix soluble silver salt with chlorides, silver chloride precipitates.
 
why is it Cl(-) + Ag(+) --> AgCl ? don't you have to balance it out? i asked my teacher and she said to use the co-efficient from the net ionic equation
 
pmahesh107 said:
why is it Cl(-) + Ag(+) --> AgCl ? don't you have to balance it out? i asked my teacher and she said to use the co-efficient from the net ionic equation

And Cl- + Ag+ --> AgCl is the balanced net ionic equation of AgCl precipitation.
 

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