Quasi-historical question about black body radiation

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Discussion Overview

The discussion revolves around the historical context and theoretical challenges associated with black body radiation, particularly focusing on the divergence of the spectrum predicted by classical physics and the attempts by physicists of the time to address this issue. Participants explore the implications of thermal equilibrium and the validity of classical thermodynamics in relation to black body radiation.

Discussion Character

  • Exploratory
  • Historical
  • Debate/contested

Main Points Raised

  • Some participants note that the divergence of the black body spectrum is seen as a failure of classical physics, which relied on basic assumptions of thermal equilibrium and Maxwell's equations.
  • There is a suggestion that relaxing the thermal equilibrium assumption could provide insights, particularly regarding high-frequency light and its interaction with matter.
  • One participant references the Ultraviolet Catastrophe and provides links to further information, indicating a broader context for the discussion.
  • Another participant discusses the derivation of the Stefan-Boltzmann law and Wien's law from classical thermodynamics, suggesting that these laws were known from experiments and may have influenced the consideration of equilibrium.
  • It is mentioned that physicists like Jeans and Rayleigh had reservations about the equipartition theorem and proposed modifications to the theory, indicating a belief that the divergence did not represent a complete failure of classical physics.
  • Some participants highlight experimental confirmations of Wien's displacement law and discuss the contributions of various physicists to the understanding of black body radiation.
  • A later post introduces a question unrelated to the main topic, asking for assistance with a mathematical problem regarding the view factor of a point source.

Areas of Agreement / Disagreement

Participants express a range of views on the implications of the divergence of the black body spectrum, with some suggesting modifications to classical theories while others emphasize the historical context. No consensus is reached regarding the interpretations of these historical attempts or the validity of the assumptions made by early physicists.

Contextual Notes

Participants acknowledge limitations in the understanding of high-frequency light and thermal equilibrium, as well as the dependence on classical thermodynamic principles. The discussion reflects ongoing uncertainties and unresolved aspects of the historical development of black body radiation theory.

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Obtaining the correct black body spectrum is one of the great triumphs of quantum physics. It is also touted as a total failure of classical physics, since with very basic assumptions, namely thermal equilibrium and the validity of Maxwell's equations, one gets the well known divergent spectrum.

I was wondering if anyone had any information about how physicists of the time tried to get around this problem. In particular, something which always seemed natural to me was the relaxing of the thermal equilibrium assumption. For example, its not obvious to me (given 19th century knowledge) why extremely high frequency light should be in thermal equilibrium with ordinary matter. Did the physicists of the time think about such high energy physics?

Beyond history, I welcome any and all comments on my comments.
 
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Wikipedia gives a derivation of the Stefan-Boltzmann law from classical thermodynamics. I think the Stefan-Boltzmann law was also already known from experiments. So maybe this was why they considered equilibrium.
http://en.wikipedia.org/wiki/Stefan–Boltzmann_law#Thermodynamic_derivation

Apparently Wien's law also has a thermodynamic derivation. I think they could also have done experiments which would verify the relation. http://en.wikipedia.org/wiki/Wien's_displacement_law

If so, both would be laws which although derivable from Planck's law, also have independent derivations from classical thermodynamics.
 
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It is also touted as a total failure of classical physics, since with very basic assumptions, namely thermal equilibrium and the validity of Maxwell's equations, one gets the well known divergent spectrum.

I was wondering if anyone had any information about how physicists of the time tried to get around this problem.

The divergence comes out because the processes of radiation are replaced by an idea of an infinite system of harmonic oscillators of unlimited frequency, and the energy of these oscillators is assumed to be ##kT##.

The assumption of equilibrium and validity of Maxwell's equations should not be blamed for the wrong result, since these are adopted in the quantum theory, from which the Planck formula is derived today.

To my knowledge, the divergence of the spectrum lead Jeans to propose that the establishment of the equilibrium may take very long time, so that the measured emission curve does not correspond to equilibrium between radiation and matter. Rayleigh had reservations to derivations of the equipartition theorem, and wrote

"
it seems to me that we must admit the failure of the law of equipartition in these extreme cases
"
in the paper "The dynamical theory of gases and of radiation".

I think these and other older physicists concerned with the thermal radiation thought that some modifications of the theory will be necessary, but they did not think that the Rayleigh-Jeans formula presents a failure of the whole then known physics. That would be an interpretation that is more properly assigned to younger physicists who developed quantum theory and its exponents, like Einstein, Debye, Heisenberg (and others).
 
atyy said:
Apparently Wien's law also has a thermodynamic derivation. I think they could also have done experiments which would verify the relation. http://en.wikipedia.org/wiki/Wien's_displacement_law

Gasiorowicz says they did have data confirming Wien's displacement law (which is different from the approximate Wien formula mentioned below). He credits Lummer and Pringsheim, and Rubens and Kurlbaum.
http://www.otto-lummer.de/waermestrahlung.html
http://blogs.osa-opn.org/OpticsLuminariesBlog/post/How-Planck-Was-Persuaded-to-Derive-the-Blackbody-Formula.aspx
http://articles.adsabs.harvard.edu/...=0&data_type=GIF&type=SCREEN_VIEW&classic=YES also credits Paschen

Planck in 1918 mentions "general, well-established displacement law by Wien", which did not need correction. The formula which is corrected by quantum calculations he calls "Wien's energy distribution law". He mentions many experimentalists. http://www.nobelprize.org/nobel_prizes/physics/laureates/1918/planck-lecture.html

Wikipedia references Wannier's text for the thermodynamic derivation. Looking on Google books, Wannier memtions a number of other properties which classical thermodyanmics gets correct from several other theorists. He says it was only the energy distribution that they could not get (I guess that's stat mech).
 
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i need to find the view factor of a point source at a distance of 120 m from one end of a square body, considered to be at origin. can you help me find the limits of integral?
for the square to be of dimension 500*500
 

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