Question about finding quantom numbers N_(n) for Schrodinger Eqn in 3D

Click For Summary
SUMMARY

The discussion centers on determining quantum numbers \( n_1, n_2, n_3 \) for the Schrödinger equation in three dimensions, specifically for cubic and non-cubic boxes. The process involves selecting initial quantum numbers, calculating the corresponding energy levels, and arranging them in order of energy. For example, the first excited states include \( E_{112} \), \( E_{121} \), and \( E_{211} \). The minimum quantum numbers are identified as \( n_1 = n_2 = n_3 = 1 \), and subsequent states are derived by incrementing these values systematically.

PREREQUISITES
  • Understanding of quantum mechanics principles
  • Familiarity with the Schrödinger equation
  • Knowledge of energy quantization in quantum systems
  • Basic concepts of cubic and non-cubic potential boxes
NEXT STEPS
  • Study the derivation of energy levels in quantum mechanics for cubic boxes
  • Learn about quantum numbers and their significance in quantum systems
  • Explore the differences in energy states for non-cubic potential boxes
  • Investigate methods for calculating energy gradients in quantum mechanics
USEFUL FOR

Students and professionals in physics, particularly those focusing on quantum mechanics, as well as educators seeking to enhance their understanding of quantum number determination and energy state calculations.

A$APFowler
Messages
1
Reaction score
0
I'm using the Modern Physics by Tipler (6th edition) book.
In sec 7.1 it talks about the first excited state being either E_(112 ) E_(121 ) E_(112).

My question is what is the process of finding the n_(1),n_(2),n_(3) quantum numbers ? How i understand you pick random values and from their find the order of energy levels. Can you give the process if would take of finding let's say the 4th excited state for both a cubic and non cubic box.

Thank you for your time.

PS: I apologize if my format is incorrect this is my fist post. The "_" represent subscript.
 
Physics news on Phys.org
Well, if the energy dependence on the quantum numbers were somehow more complicated, you could for example calculate the gradient to find some minimum values, and go from there. In this case, the minimum is trivially at 1,1,1. After you have that sorted, then all you can really do is calculate the energies for nearby quantum numbers. So you'd find E111, E112, ... , E122, E212, and so on. Then you just arrange the states according to their energy.
 

Similar threads

  • · Replies 3 ·
Replies
3
Views
10K
  • · Replies 5 ·
Replies
5
Views
3K