Question on the degeneracies of a thermodynamic system

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SUMMARY

The discussion focuses on calculating the heat capacity of a thermodynamic system with three energy levels: \(E_1=\varepsilon\), \(E_2=2\varepsilon\), and \(E_3=3\varepsilon\), where the degeneracies are \(g(E_1)=1\), \(g(E_2)=2\), and \(g(E_3)=1\). The partition function \(Z\) is derived using the formula \(Z=\sum_i g_ie^{-\beta \varepsilon_i}\), leading to the expression \(Z=g_1e^{-\beta \varepsilon} + 2g_2e^{-\beta 2\varepsilon} + g_3e^{-\beta 3\varepsilon}\). The final heat capacity is given by \(C=2k\frac{x^2e^x}{(e^x+1)^2}\), where \(x=\beta \varepsilon\). Understanding the role of degeneracies in the partition function is crucial for grasping the heat capacity calculation.

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  • Understanding of statistical mechanics concepts, particularly partition functions.
  • Familiarity with the Boltzmann factor and its application in thermodynamics.
  • Knowledge of heat capacity definitions and calculations in thermodynamic systems.
  • Basic understanding of energy levels and degeneracies in quantum mechanics.
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  • Study the derivation of the partition function in statistical mechanics.
  • Learn about the implications of degeneracies on thermodynamic properties.
  • Explore the relationship between internal energy and heat capacity in thermodynamic systems.
  • Investigate the application of the canonical ensemble in statistical physics.
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Students and professionals in physics, particularly those focusing on statistical mechanics and thermodynamics, as well as anyone interested in understanding heat capacity calculations in systems with degeneracies.

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Homework Statement


A system possesses three energy levels $$E_1=\varepsilon$$ $$E_2=2\varepsilon$$ $$E_3=3\varepsilon$$ with degeneracies $$g(E_1)=g(E_3)=1$$ $$g(E_2)=2$$. Find the heat capacity of the system.

Homework Equations


$$\beta=\frac{1}{kT}$$
$$Z=\sum_i g_ie^{-\beta \varepsilon_i} \ $$

The Attempt at a Solution


From a beginner's perspective I know to apply the partition function for a system with degeneracies as the first step in order to be able to obtain more information about the system. Thus,

$$Z=g_ie^{-\beta \varepsilon} + 2g_ie^{-\beta 2\varepsilon} + g_ie^{-\beta 3\varepsilon}$$

But I still don't quite understand what's going on here. Also, the hint at the back of the book (Statistical Physics by F. Mandl) simply says to take the zero of the energy scale at $E_1=0$ and then proceeds to give the final answer as: $$C=2k\frac{x^2e^x}{(e^x+1)^2}$$

But this isn't really helpful in understanding the concept. What do the degeneracies of a system do to the solution of the partition function?
 
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Heat capacity is the heat added per change in temperature. So find the expectation value of the internal energy as a function of temperature, and then take its derivative with respect to temperature.
 

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