Quick QM: Why Does Schrodinger Eq Being 1st Order Matter?

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Discussion Overview

The discussion centers on the significance of the Schrödinger equation being first order in time and its implications for the probability interpretation in quantum mechanics. Participants explore theoretical aspects, mathematical reasoning, and conceptual clarifications related to the equation's structure.

Discussion Character

  • Exploratory, Technical explanation, Conceptual clarification, Debate/contested

Main Points Raised

  • One participant questions the importance of the Schrödinger equation being first order in time for the probability interpretation.
  • Another suggests investigating the separation of variables method, noting that the time-dependent part of the solution leads to a probability density that is time-dependent.
  • A historical perspective is introduced, mentioning Schrödinger's initial work with a relativistic equation that resulted in negative probability densities.
  • Some participants express uncertainty about how the order of time dependence affects the probability interpretation, with one noting a lack of imagination in conceptualizing alternatives to the first-order form.
  • Concerns are raised about the implications of different orders in time potentially leading to negative probabilities, despite the norm squared of the wave function remaining positive.

Areas of Agreement / Disagreement

Participants express varying degrees of understanding and uncertainty regarding the implications of the first-order nature of the Schrödinger equation. There is no consensus on how changes to the order of time dependence would affect probability interpretations.

Contextual Notes

Some participants acknowledge limitations in their understanding of the implications of different orders in time and how they relate to the derivation of probabilities from the Schrödinger equation.

Thrice
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The Schrödinger eq is 1st order in t. Why does that matter to the probability interpretation?

Should be an easy question, but I can't seem to get it.
 
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Here's a suggestion you might want to investigate. When solving the SE by the method of separation of variables, we find that the time dependent part of the solution is [itex]\exp{iEt/\hbar}[/itex], and the position dependent part satisfies the time-dependent SE. Denote [itex]\psi(x)[/itex] the solution to the time dependent SE for a given potential. Then the general solution to the SE is [itex]\Psi(x,t)=\psi(x)e^{iEt/\hbar}[/itex], and according to the Born interpretation, [itex]\Psi \Psi^*[/itex] is a probability density function for the position of the particle. But [itex]\Psi \Psi^* = \psi\psi^*[/itex]. I.e. the probability density is is time dependent!

So the question is, would the time dependent part of the [itex]\Psi[/itex] still be such that the probability is time dependent if the t "dependance" of the SE was not of first order?
 
Interestingly, Schrödinger originally started with a relativistic equation, but didn't know what to do with the negative probability densities that resulted, so came up with the final non-relativistic equation instead.
 
quasar987 said:
Here's a suggestion you might want to investigate. When solving the SE by the method of separation of variables, we find that the time dependent part of the solution is [itex]\exp{iEt/\hbar}[/itex], and the position dependent part satisfies the time-dependent SE. Denote [itex]\psi(x)[/itex] the solution to the time dependent SE for a given potential. Then the general solution to the SE is [itex]\Psi(x,t)=\psi(x)e^{iEt/\hbar}[/itex], and according to the Born interpretation, [itex]\Psi \Psi^*[/itex] is a probability density function for the position of the particle. But [itex]\Psi \Psi^* = \psi\psi^*[/itex]. I.e. the probability density is is time dependent!

So the question is, would the time dependent part of the [itex]\Psi[/itex] still be such that the probability is time dependent if the t "dependance" of the SE was not of first order?
Ok I understand what you said there (I think), but I can't make the jump to what would happen if it wasn't 1st order in t. I know how to derive the equation from dealing with wave packets, I know why it's 1st order & how to get the time independent SE eigenvalue equation.

Call it a lack of imagination. I can't see how it could be different. I know the difference between the SE & the familiar wave equation, but I can't see how to get probabilities out of the latter.
 
It should have to do with what Daverz said. I.e. that a different order in t will give us negative probabilities... but how could that be? Whatever the solution [itex]\Psi(x,t)[/itex] to a modified SE, the complex conjugate of [itex]\Psi[/itex] is still it's norm squared, which is still positive no matter what. :confused:
 
Bump. I was going through old posts & needed some closure here. Thanks to whoever moved this.
 

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