Radial probability distribution (rpd)

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SUMMARY

The discussion centers on the concept of Radial Probability Density (RPD) in quantum mechanics, specifically defined as R(r), the square of the radial wavefunction. The calculation of RPD involves the volume of a spherical shell, expressed as rpd = R² × 4πr², where the differential volume element dr is effectively canceled out. Participants clarify that the density function is derived from the cumulative distribution function F(r), with R(r) being the derivative dF(r)/dr, emphasizing the relationship between probability density and volume in spherical coordinates.

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brainyman89
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Radial Probability Density = R(r) : Square of the Radial Wavefunction
The required volume is determined by the volume of the SPHERICAL SHELL enclosed between a sphere of radius (r+dr) and a sphere of radius r

rpd = radial probability density × volume of the spherical shell = R2 × 4πr2 drhow then did they cancel the dr and directly write:
rpd = R2 × 4πr2

??

also how could only radial probability be multiplied by volume? shouldn't the whole wave function be multiplied by the volume?
 
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The density function is the derivative of the distribution - that's where the dr went.
 
mathman said:
The density function is the derivative of the distribution - that's where the dr went.

derivative with respect to what?
 
brainyman89 said:
derivative with respect to what?

The cumulative distribution is F(r) and the density function R(r) = dF(r)/dr
 

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