Ratio of molar mass 2 component ideal solution

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Discussion Overview

The discussion revolves around a homework problem involving the calculation of the ratio of molar masses of two components in an ideal solution based on vapor pressure data. The scope includes mathematical reasoning and technical explanation related to ideal solutions and vapor pressures.

Discussion Character

  • Homework-related, Mathematical reasoning

Main Points Raised

  • One participant presents a method to calculate the ratio of molar masses based on vapor pressures and the mass of components.
  • Another participant questions the rounding of intermediate results, suggesting that it may affect the accuracy of the final answer.
  • A subsequent reply indicates that using unrounded values yields a different ratio of molar masses.
  • There is a reminder about the importance of significant digits in calculations.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the correct ratio of molar masses, as different approaches to rounding lead to varying results.

Contextual Notes

Limitations include potential issues with rounding and significant digits that may affect the accuracy of the calculations presented.

sandra
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Homework Statement


Component 1 and 2 form an ideal solution. The vapor pressure of pure component 1 is 13.3kPa at 298K, and the corresponding vapor pressure of component 2 is approximately zero. If the addition of 1.00 g of component 2 to 10.0g of component 1 reduces the total vapor pressure to 12.6 kPa, find the ratio of the molar mass of component 2 to that of component 1.

Homework Equations


x1 = p/p*
x1 = n1/(n1+n2)
n2=n1(1/x1-1)

The Attempt at a Solution


x1 = p/p* = 12.6/13.3 = 0.947
Mass of component 1 = m1
n1 = 10g/m1
x1 = n1/(n1+n2)
n1+n2= n1/x1
n2=n1(1/x1-1)
=10/m1(1/0.947 - 1) = 0.5597/m1
m2=1/(0.5597/m1) = m1/0.5597
m1/m2 = 0.5597
Can anybody tell me if this looks right? thank you
 
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Close. Have you used rounded down 0.947 for calculations? You should not round down intermediate results.

--
methods
 
If I don't round I get m1/m2=0.5556
Is that right? Thanks!
 
Watch significant digits.

--
methods
 

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