Redox Reaction: Adding Excess Acidified KMnO4 to Ammonium Iron(II) Sulfate

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Discussion Overview

The discussion revolves around the redox reaction that occurs when excess acidified potassium permanganate is added to an ammonium iron(II) sulfate solution. Participants explore how to write the overall redox equation for this process, including identifying the products formed.

Discussion Character

  • Homework-related
  • Exploratory
  • Technical explanation

Main Points Raised

  • One participant expresses uncertainty about how to begin writing the overall redox equation and what products are formed.
  • Another participant suggests starting with a balanced equation and inquires if specific rules for redox reactions were provided.
  • A question is raised about the key characteristic of potassium permanganate that is relevant to the reaction.
  • Participants discuss the properties of potassium permanganate, noting its solubility in water and its role as a strong oxidizing agent.
  • A participant proposes a reduction half-equation for potassium permanganate, indicating its reduction to manganese ions.
  • There is a suggestion to combine the reduction half-equation with the oxidation half-equation for iron(II) being oxidized to iron(III) ions.

Areas of Agreement / Disagreement

Participants generally agree on the role of potassium permanganate as an oxidizing agent and the need to combine half-equations, but the overall redox equation remains unresolved as participants are still in the process of formulating it.

Contextual Notes

There is a lack of consensus on the specific products formed in the reaction, and participants have not fully established the balanced overall equation.

Who May Find This Useful

Students studying redox reactions, particularly those working on homework related to chemical equations and reaction mechanisms.

danago
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Homework Statement


Excess acidified potassium permanganate is added dropwise to an ammonium iron(II) sulfate solution. Write an overall redox equation for this process.

2. The attempt at a solution
Well I am not really sure what to do. I don't know what products are being formed. What should i do in a situation like this?
 
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Start with a balanced equation. Were you given the rules to follow for a redox reaction?
 
What is the one thing that you neeed to know about potassium permanganate?
 
How do i write a balanaced equation though? I don't know what the products are
 
Gokul43201 said:
What is the one thing that you neeed to know about potassium permanganate?

Its soluble in water?
 
Lots of things are soluble in water.

I quote from the first paragraph of the wiki on potassium permanganate:

Potassium permanganate is the chemical compound KMnO4. In this salt, manganese is in the +7 oxidation state. The salt is also known as "permanganate of potash" and "Condy's crystals". The permanganate ion is a strong oxidizing agent. It dissolves in water to give deep purple solutions, evaporation of which gives prismatic purple-black glistening crystals. It has a sweet taste and is odourless.
 
Ok, so its an oxidising agent, and therefore, itself reduced. I think this is the correct equation for its reduction:

[tex] MnO_4 ^ - _{(aq)} + 8H^ + _{(aq)} + 5e^ - \to Mn^{2 + } _{(aq)} + 4H_2 O_{(l)} [/tex]

Would i just combine that with the half equation of iron (II) being oxidised to iron (III) ions?
 
Yup, you got it! :approve:
 
Ahh ok. Thanks :)
 

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