Salt bridge and electical field

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SUMMARY

A salt bridge in a Galvanic cell ensures that there is no electrical field between the solutions of the two half-cells, resulting in an ideal scenario where the electrical potential between both solutions is zero. The electric field inside the conductor is zero, as any net electric field would cause charge movement, violating equilibrium conditions. Calculating the difference in electrochemical potential between the solutions can be achieved by analyzing the concentrations of ions in each solution. Alternative arrangements for Galvanic cells, such as using two electrodes in a single beaker, can provide more accurate voltage measurements by minimizing junction potential errors.

PREREQUISITES
  • Understanding of Galvanic cells and their components
  • Knowledge of electrochemical potential and its significance
  • Familiarity with ion conduction in solutions
  • Basic principles of electric fields and equilibrium in conductors
NEXT STEPS
  • Study the Nernst equation for calculating electrochemical potential differences
  • Explore the concept of junction potential in electrochemical measurements
  • Research alternative configurations for Galvanic cells and their advantages
  • Learn about the role of salt bridges in maintaining charge balance in electrochemical cells
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Chemistry students, electrochemists, and researchers interested in the principles of Galvanic cells and electrochemical measurements.

wnvl2
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Is it correct that a salt bridge in a Galvanic cell makes that there is no electrical field between the solutions of the two hallf cells? Does that mean that the electrical potential (I do not write electrochemical potential) between both solutions is zero in an ideal world?

Is it also possible to calculate the difference in electrochemical potential between both solutions. I mean the solutions not the electrodes in the solutions. How should that be done?
 
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wnvl2 said:
Is it correct that a salt bridge in a Galvanic cell makes that there is no electrical field between the solutions of the two hallf cells? Does that mean that the electrical potential (I do not write electrochemical potential) between both solutions is zero in an ideal world?
The solutions and salt bridge are 'conductors', except + and - ions carry charge.

In general "The electric field inside the conductor is zero. (Any net electric field in the conductor would cause charge to move since it is abundant and mobile. This violates the condition of equilibrium: net force = 0.)" http://hyperphysics.phy-astr.gsu.edu/hbase/electric/gausur.html#c2

See the discussion here:
https://chem.libretexts.org/Courses...ELECTRO-CHEMISTRY/17.1:_Electrochemical_Cells
Galvanic cells can have arrangements other than the examples we have seen so far (with a salt bridge). For example, the voltage produced by a redox reaction can be measured more accurately using two electrodes immersed in a single beaker containing an electrolyte that completes the circuit. This arrangement reduces errors caused by resistance to the flow of charge at a boundary, called the junction potential.
 
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