Scalar product of position vectors

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find values of t for f'(t) =0

I don't understand the significance of r.r, however.

Thanks
 
Well, r is the vector that describes the difference in position.
r . r is the square of its length. So the square of the distance between the particles.

Note that minimizing (maximizing) the distance is equivalent to minimizing (maximizing) the square of the distance.