Schrodinger Equation: No Higher Powers of ψ

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Discussion Overview

The discussion revolves around the nature of the Schrödinger equation, specifically addressing the claim that second or higher powers of the wave function ψ do not appear in the equation. Participants explore the implications of linearity in the context of quantum mechanics, particularly regarding solutions and superposition.

Discussion Character

  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant questions the statement that "second or higher powers of ψ do not appear," citing the presence of the second derivative in the Schrödinger equation.
  • Another participant clarifies that "linear" refers to the absence of terms like (dψ/dx)^2 or ψ^2, emphasizing the distinction between derivatives and powers of ψ.
  • A further contribution highlights the significance of linearity in the equation, noting that if two wave functions are solutions, any linear combination of them is also a solution, which is crucial for the concept of "wave packets" in quantum mechanics.
  • One participant reiterates the linear nature of the Schrödinger equation and its implications for solutions, stating that any linear combination of solutions remains a valid solution.

Areas of Agreement / Disagreement

Participants appear to agree on the definition of linearity in the context of the Schrödinger equation, but there is some disagreement regarding the interpretation of the presence of derivatives versus powers of ψ.

Contextual Notes

The discussion does not resolve the apparent confusion regarding the terminology used to describe the linearity of the Schrödinger equation and its implications for the wave function.

logearav
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ψ and its derivatives occur only linearly in the Schrödinger equation, that is, second or higher powers of these quantities do not appear in the equation.
Schrödinger equation for a free particle is
i[itex]\hbar[/itex]∂ψ(x,t)/∂t = (-[itex]\hbar[/itex]2/2m)(∂2ψ(x,t)/∂x2)
Here (∂2ψ(x,t)/∂x2) is second power of ψ. Then how can we justify the statement "second or higher powers of ψ do not appear"?
 
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That's the second derivative. The statement "linear" means no terms like (dψ/dx)^2 or ψ^2 appear.
 
To follow that up, the key issue with the equation being linear is that if two wave functions are possible solutions (like two plane waves in your example), then any linear superposition of them is also a solution. This gives us the concept of "wave packets", and is important in a lot of quantum mechanics.
 
Thanks for your replies Matterwave and Ken G
 
logearav said:
ψ and its derivatives occur only linearly in the Schrödinger equation, that is, second or higher powers of these quantities do not appear in the equation.
Schrödinger equation for a free particle is
i[itex]\hbar[/itex]∂ψ(x,t)/∂t = (-[itex]\hbar[/itex]2/2m)(∂2ψ(x,t)/∂x2)
Here (∂2ψ(x,t)/∂x2) is second power of ψ. Then how can we justify the statement "second or higher powers of ψ do not appear"?

The Schrödinger equation is a differential linear equation in ψ.

For a free particle it is

i[itex]\hbar[/itex]∂/∂t ψ = K ψ

Since it is linear this means that if ψ1 and ψ2 are solutions, then any linear combination ψT = c1ψ1 + c2ψ2 is a solution as well.
 

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