SF4 has Exactly 5 Electron Pairs Around Central Atom

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SUMMARY

The species with exactly five pairs of electrons around the central atom is SF4. This conclusion is reached by counting the valence electrons: sulfur contributes 6 electrons, while each of the four fluorine atoms contributes 1 electron, totaling 10 electrons or 5 pairs. The other options, ClF5, SF5–, and XeF4, do not meet the criteria as they either exceed or do not reach five pairs of electrons. Understanding the electron pair geometry is crucial for identifying such molecular structures.

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  • Valence shell electron pair repulsion (VSEPR) theory
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  • Familiarity with the concept of d-orbitals in molecular structures
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gsingh2011
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The question is: Which species has exactly five pairs of electrons around
the central atom?
(A) ClF5 (B) SF4 (C) SF5 (D) XeF4

The answer is B. Can someone explain why? I'm not too good with these geometries that use the d-orbital.
 
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There are no d orbitals involved. You just have to count the number of valence electrons. In the first example there are 7 electrons from Cl and 5 from Fluorine, i.e. 12 in total or six pairs. Analogously for the other cases.
 

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