Shifting Constraints in the Particle in a Box System

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SUMMARY

The discussion focuses on the implications of shifting constraints in the Particle in a Box system, specifically transitioning the boundaries from x = -a/2 to a/2, to x = 0 to a. Participants confirm that this transformation is valid, allowing for the use of eigenstates defined by the equation φ_n = √(2/a) sin(nπx/a) without altering the fundamental properties of the system. The invariance of the Schrödinger equation under coordinate transformations is emphasized, highlighting that the eigenstates can be transformed into cosine functions while satisfying new boundary conditions.

PREREQUISITES
  • Understanding of quantum mechanics, particularly the Particle in a Box model.
  • Familiarity with the Schrödinger equation and its applications.
  • Knowledge of eigenstates and their significance in quantum systems.
  • Basic grasp of coordinate transformations in physics.
NEXT STEPS
  • Study the implications of boundary conditions on eigenstates in quantum mechanics.
  • Explore coordinate transformations and their effects on quantum systems.
  • Investigate the role of potential energy in the Particle in a Box model.
  • Learn about the mathematical derivation of cosine solutions in quantum mechanics.
USEFUL FOR

Students and professionals in physics, particularly those specializing in quantum mechanics, as well as researchers interested in the mathematical foundations of quantum systems.

Domnu
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I was just wondering... if a problem involved a particle which was constrained to move from x = -a/2 to a/2 and asked you to find it's properties (not position, though), could you just "shift" the entire system from x = -a/2, a/2 to x = 0 to a?

Also, let's say that a question asked for the probability of the particle being present from x = -a/2 to a/10 (assuming the particle is constrained from -a/2 to a/2). Could we just shift the box to 0 to a and find the probability of the particle being present in the areas between 0 and a/10+a/2 = 3a/5 ?

This would be really useful, because I can still use the eigenstates of the energy function for a particle in the box scenario,

[tex]\phi_n = \sqrt{\frac{2}{a}}\sin \frac{n\pi x}{a}[/tex]

By the way, this is all assuming that no potential energy is present in the system.
 
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Yes, the Schrödinger equation is invariant under coordinate changes [tex]x \to x + b[/tex].
You'll also find that if you do the transformation on your eigenstates, you end up with cosines, which are solutions to the SE with the new boundary condition.
 

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