# Solve Schrodinger Equation for Infinite Square Well - Q1

• oddiseas
In summary, the conversation discusses the topic of quantum mechanics, specifically the concept of eigenfunctions and the use of operators. The conversation also includes a question involving an infinite square well and finding the wave function \Psi for a quantum mechanical system. The solution involves applying the Hamiltonian operator and solving the resulting differential equation to find a specific solution.
oddiseas

## Homework Statement

I have just started quantum mechanics bacuase i want to prepare for my class starting in march. I must say so far i find it very confusing: I could use some help with this problem and in addition some explanation on the logic of what it all means.

i get that this theory combines classical mechanics with the wave nature of particles and that the eigenfunctions correspond to standing waves at certain energy levels. But if a particle is localised, what information are we actually getting from its wave function? and how is the wave produced?

Anyway the question i am working on deals with an infinite square well.

Q1)
At t=0 a quantum mechanical system is described by the eigenfunction
$$\Psi$$=iA(L-x^2)

-L<=X<=L

a) Clearrly stating your reasons indicate whether or not $$\Psi$$ is an eigenfunction of the kinetic energy operation;

b) assuming the system is in a well defined eigenstate with total energy E, find the wave function $$\Psi$$

## The Attempt at a Solution

a)$$\Psi_x_x$$=-2iA. This does not match the kinetic operator from schrodingers equation. Anyhow i don't understand what the operator means, so if anyone does i could use some help.

b)Solving for the initial conditions, and then finding A by evaluating the integral of|$$\Psi^2$$| i get:
$$\Psi_n(x)$$= $$\frac{1}{2\sqrt{L}}$$sin(npix/L)

Then i tried using the Fourier series to find the coefficients
but i get something that looks wrong,

i get one value for n=0, a different one for n= even and another for n=odd.

Anyway i don't have the answer to this question and i am getting confused so it would be great if i could see a worked solution.

Last edited:
The idea of quantum mechanics (as you may know) is that you replace the plain old variables of classical mechanics with operators. With position and momentum, you have to pick one of them to remain a variable,
$$x \to x$$
and then the other one becomes a derivative,
$$p \to i\hbar\frac{\partial}{\partial x}$$
Then you can build up all sorts of other operators using familiar formulas from classical mechanics. Like $H = p^2/2m$ (the Hamiltonian). In quantum mechanics, that becomes
$$H = -\frac{\hbar^2}{2m}\frac{\partial^2}{\partial x^2}$$
When you want to figure out whether a wavefunction is an eigenfunction of that operator, you check to see whether
$$H\Psi = E\Psi$$
for some value $E$ - that is, when you apply the operator (in this case, a second derivative and then multiplying by a constant) to the function, do you get back a multiple of the same function? If so, it's an eigenfunction of that operator. If not, it's not. That's all that's involved in part (a); just check the result you got from applying the operator to $\Psi$ and see if it's a multiple of $\Psi$.

The significance of the eigenfunctions is that they're the only wavefunctions for which the value of the observable corresponding to that operator is well defined. For example, considering the operator $H$, only eigenfunctions of $H$ have a definite value of energy. Non-eigenfunctions are a mix of different states with different values of energy. So in part (b), it's telling you to assume that $\Psi$ (different $\Psi$ from part (a)) is an eigenstate, or eigenfunction, of the Hamiltonian operator. That means that you know it has to satisfy the equation
$$H\Psi = E\Psi$$
for some value $E$. (They didn't give you a numeric value for E, but consider it a "known quantity;" you can use it in your solution.) When you substitute in the actual definition of $H$, you get a differential equation, which you can solve to get one unique solution. (If you didn't "know" the value of $E$, then yes, you'd have to find a generic solution, like you did. But if you consider $E$ known, and remember that you're talking about one eigenstate with one particular value of the energy, you can find a specific solution to the equation.)

Thanks, that's helpful, but i am still having trouble finding the solution.If it satisfies the differential equation, then the general solution is Acosmx +Bsinmx, where m=$$\sqrt{2mK}$$/h and the solution becomes:

$$\sum_{n=0}^\infty\ D*sin(npix/L)\*exp(iEt/h)$$

Where the value D is determined by the initila eigen function:

If someone can solve this question i would like to see what the solution is.

oddiseas said:
Thanks, that's helpful, but i am still having trouble finding the solution.If it satisfies the differential equation, then the general solution is Acosmx +Bsinmx, where m=$$\sqrt{2mK}$$/h
Stop right there. Assuming that by $K$ you mean $E$, you've got it. Now figure out what conditions A and B need to satisfy so that they are consistent with the required boundary conditions.

## What is the Schrodinger Equation for the Infinite Square Well?

The Schrodinger Equation for the Infinite Square Well is a fundamental equation in quantum mechanics that describes the behavior of a particle confined within a potential well with infinitely high walls. It is given by:
ψ(x,t)=√(2/L)sin(nπx/L)e^(-iE_nt/ℏ)
where ψ is the wave function, x is the position of the particle, t is time, L is the width of the well, n is the quantum number, E_n is the energy level, and ℏ is the reduced Planck's constant.

## What is the physical significance of the Infinite Square Well potential?

The Infinite Square Well potential is a simplified model used to study the behavior of quantum particles in a confined space. It represents a particle being trapped within a region with infinitely high potential walls, where the particle's energy is quantized and can only take on certain discrete values. This potential is often used to understand the behavior of electrons in an atom or a particle in a box.

## How do you solve the Schrodinger Equation for the Infinite Square Well?

To solve the Schrodinger Equation for the Infinite Square Well, one must apply boundary conditions and use separation of variables to obtain the wave function solution. These boundary conditions include the wave function being continuous and its derivative being discontinuous at the edges of the well. The solution will result in a set of energy levels and corresponding wave functions for the particle in the well.

## What is the significance of the energy levels in the Infinite Square Well potential?

The energy levels in the Infinite Square Well potential represent the quantized energy states of the particle within the well. Each energy level corresponds to a specific wave function and has a unique energy value. The energy levels are equally spaced and the energy gap between them decreases as the quantum number increases, showing the particle's confinement within the well.

## What is the probability of finding a particle in a specific energy state in the Infinite Square Well potential?

The probability of finding a particle in a specific energy state in the Infinite Square Well potential is given by the square of the amplitude of the corresponding wave function. This means that the probability is higher for energy states with larger amplitudes and decreases as the energy level increases. Additionally, the probability distribution is symmetrical around the center of the well, indicating that the particle is equally likely to be found anywhere within the well.

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